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塔中奥陶系储层硫化氢成因及主控因素 被引量:16
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作者 程汉列 王连山 +3 位作者 高创波 单永乐 李勇 冯毅 《地质找矿论丛》 CAS CSCD 2018年第4期604-610,共7页
塔中奥陶系储层内硫化氢广泛分布,由于其剧毒、易溶于油水中、腐蚀性强,给勘探开发工作带来一定难度。为了弄清奥陶系储层的硫化氢成因及分布规律,在分析现有关储层中H_2S来源研究成果的基础上,结合塔中地区奥陶系碳酸盐岩中的矿物组分... 塔中奥陶系储层内硫化氢广泛分布,由于其剧毒、易溶于油水中、腐蚀性强,给勘探开发工作带来一定难度。为了弄清奥陶系储层的硫化氢成因及分布规律,在分析现有关储层中H_2S来源研究成果的基础上,结合塔中地区奥陶系碳酸盐岩中的矿物组分、H_2S及其硫碳同位素分析来探讨其H_2S原因。结果表明:三期方解石交代硫酸盐矿物,且硫酸盐未被TSR还原;奥陶系内硫化氢硫同位素普遍比寒武系内硫化氢硫同位素低;奥陶系内硫化氢硫同位素和地层水硫酸根硫同位素具有伴生关系,TSR发生在烃水过渡带;TSR反应物与硫化氢含量无相关关系,并出现了沥青质碳同位素值的负偏;甲烷碳同位素值与硫化氢含量无相关关系,甲烷并未参与TSR。奥陶系与寒武系内硫化氢为不同阶段各自的产物;硫化氢生成时期为奥陶系良里塔格组(O_3l)和鹰山组(O_(1-2)y)内TSR发生在晚燕山期-喜山期,寒武系内TSR发生在晚海西期和晚燕山期-喜山期。总体上,奥陶系内硫化氢为原地TSR成因,受控于走滑断裂注入寒武系高矿化度、富镁地层水和油气,以及沿I号断裂运移的贫硫化氢干气稀释作用。 展开更多
关键词 塔中地区 奥陶系 碳酸盐岩 硫化氢 硫同位素组成 新疆
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基于应力应变曲线的页岩脆性指标分析 被引量:8
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作者 桑峰军 程汉列 +4 位作者 张晓燕 杨国平 赵建锋 符彩云 张冲 《河南理工大学学报(自然科学版)》 CAS 北大核心 2021年第5期63-70,共8页
页岩脆性是评价页岩气储层是否可压的一个重要指标,是储层能否实现商业开采的关键。以南方海相龙马溪组富有机质页岩为研究对象,开展了单三轴压缩试验,依据岩石应力应变曲线建立新的脆性评价指标,并进行验证,在此基础上研究了页岩的脆... 页岩脆性是评价页岩气储层是否可压的一个重要指标,是储层能否实现商业开采的关键。以南方海相龙马溪组富有机质页岩为研究对象,开展了单三轴压缩试验,依据岩石应力应变曲线建立新的脆性评价指标,并进行验证,在此基础上研究了页岩的脆性各向异性特征,结果表明:提出的脆性指标可以较好地反映页岩的脆性特征,标准化系数分别取λ=0.4和η=0.6时效果最好;南方海相龙马溪组页岩储层具有较强的脆性特征,可将其划分为高可压性储层;页岩的脆性指标随着围压增加逐渐降低,降低的速率逐渐减小;页岩的应力应变曲线5个阶段比较明显,随着围压增加,压密阶段逐渐缩短,屈服阶段逐渐变长,残余强度随着围压几乎线性增加;随着围压增加,页岩的峰值强度、弹性模量和软化模量都表现出明显的增加趋势,增幅分别为105.17%,71.74%和97.75%;页岩的脆性指标随着层理倾角增加先减小后增加,表现出"U"形变化规律,在层理倾角θ=0°时取得最大值,θ=30°时取得最小值,各向异性系数高达1.991,具有明显的各向异性特征。 展开更多
关键词 龙马溪组页岩 脆性指标 单三轴压缩试验 力学参数 应力应变曲线 各向异性
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水培绿萝对水体有机紫外吸收剂的净化研究 被引量:1
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作者 吴玥 程函列 +3 位作者 厉益利 孙亭 戚高晟 邵波 《亚热带水土保持》 2018年第3期19-23,共5页
防晒剂中的有机紫外吸收剂逐渐污染天然水体,而对氨基苯甲酸是有机紫外吸收剂中的一种常用成分。本文通过研究发现对氨基苯甲酸水体中绿萝的生长良好,无太大影响,从而设置不同初始对氨基苯甲酸浓度、培养时间、培养液pH与培养温度,探讨... 防晒剂中的有机紫外吸收剂逐渐污染天然水体,而对氨基苯甲酸是有机紫外吸收剂中的一种常用成分。本文通过研究发现对氨基苯甲酸水体中绿萝的生长良好,无太大影响,从而设置不同初始对氨基苯甲酸浓度、培养时间、培养液pH与培养温度,探讨绿萝是否能够降解对氨基苯甲酸及其降解效率。实验结果显示:绿萝对各种浓度对氨基苯甲酸的溶液都有着不错的净化能力;弱酸性条件下吸收降解能力最强,碱性条件的水体对绿萝吸收降解对氨基苯甲酸的效率有较大影响;对培养温度不是很敏感。 展开更多
关键词 绿萝 植物净化 对氨基苯甲酸 降解
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算井子地段地表岩体结构面发育程度评价 被引量:4
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作者 魏翔 芦安贵 +1 位作者 程汉列 游声刚 《河海大学学报(自然科学版)》 CAS CSCD 北大核心 2022年第1期96-101,共6页
为了探讨结构面发育程度对高放废物地质处置库选址的影响,以甘肃北山算井子地段岩体为研究对象,通过调查地表岩体节理和断层几何特征,采用数理统计方法获得节理产状、密度、间距、迹长和断层产状、断裂带宽度和断层泥厚度等统计数据,提... 为了探讨结构面发育程度对高放废物地质处置库选址的影响,以甘肃北山算井子地段岩体为研究对象,通过调查地表岩体节理和断层几何特征,采用数理统计方法获得节理产状、密度、间距、迹长和断层产状、断裂带宽度和断层泥厚度等统计数据,提出多尺度结构面综合评价指标来评价岩体结构面发育程度。结果表明:BS22和BS23钻孔周围分别发育4个和5个节理优势组,节理产状服从正态分布;BS22和BS23钻孔周围岩体节理平均中点面密度分别为0.037 m^(-2)和0.035 m^(-2),平均迹长分别为20.38 m和17.39 m;解译出断层F1产状为35°∠85°,延伸长度为4.49 km;BS22钻孔周围岩体结构面发育程度更低,更适合作为我国高放废物处置库建造场址。 展开更多
关键词 地表岩体 结构面几何特征 结构面发育程度 高放废物地质处置 算井子地段
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A Strain Rate Dependent Constitutive Model for the Lower Silurian Longmaxi Formation Shale in the Fuling Gas Field of the Sichuan Basin,China 被引量:3
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作者 HOU Zhenkun LI Xianwen +4 位作者 ZHANG Yanming LIANG Huqing GUO Ying cheng hanlie GAO Ruchao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2019年第4期972-981,共10页
Shale,as a kind of brittle rock,often exhibits different nonlinear stress-strain behavior,failure and timedependent behavior under different strain rates.To capture these features,this work conducted triaxial compress... Shale,as a kind of brittle rock,often exhibits different nonlinear stress-strain behavior,failure and timedependent behavior under different strain rates.To capture these features,this work conducted triaxial compression tests under axial strain rates ranging from 5×10-6 s-1 to 1×10-3 s-1.The results show that both elastic modulus and peak strength have a positive correlation relationship with strain rates.These strain rate-dependent mechanical behaviors of shale are originated from damage growth,which is described by a damage parameter.When axial strain is the same,the damage parameter is positively correlated with strain rate.When strain rate is the same,with an increase of axial strain,the damage parameter decreases firstly from an initial value(about 0.1 to 0.2),soon reaches its minimum(about 0.1),and then increases to an asymptotic value of 0.8.Based on the experimental results,taking yield stress as the cut-off point and considering damage variable evolution,a new measure of micro-mechanical strength is proposed.Based on the Lemaitre’s equivalent strain assumption and the new measure of micro-mechanical strength,a statistical strain-rate dependent damage constitutive model for shale that couples physically meaningful model parameters was established.Numerical back-calculations of these triaxial compression tests results demonstrate the ability of the model to reproduce the primary features of the strain rate dependent mechanical behavior of shale. 展开更多
关键词 strain rates triaxial compression tests damage variable constitutive model Longmaxi Formation shale
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Rock Mass Characteristics in Beishan,A Preselected Area for China's High-Level Radioactive Waste Disposal 被引量:2
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作者 WEI Xiang GUO Ying +4 位作者 cheng hanlie MENG Xiangdong cheng Mingqian YANG Ting XU Chunmei 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2019年第2期362-372,共11页
Geological and hydrological characteristics, joint geometric features, rock physical and mechanical properties and rock mass quality are studied in the Beishan area, preselected for China5 s high-level radioactive was... Geological and hydrological characteristics, joint geometric features, rock physical and mechanical properties and rock mass quality are studied in the Beishan area, preselected for China5 s high-level radioactive waste(HLW) disposal engineering. A comprehensive survey method is developed to study joint geometric features in the outcrop and samples from borehole BS06 into the Xinchang rock mass were tested. The optimal joint sets are determined by rose diagrams and equal-area lower hemisphere plots of joint poles. Results show that: 1) the distribution of joint occurrence obeys a normal distribution, while the distribution of joint spacing obeys a negative exponential distribution; 2) concentric circular and tangent circular sampling windows are applied to study the trace length and the trace midpoint density. Results indicate that tangent circular sampling window is more stable and reasonable; 3) Beishan granite shows high density, low porosity and high strength based on many laboratory tests and the physical properties and mechanical properties are closely related; and4) a synthesis index, Joint Structure Rating(JSR), is applied to evaluate the quality of rock mass. Through the research results of rock mass characteristics, the Xinchang rock mass in the Beishan preselected area has the favorable conditions for China's HLW disposal repository site. 展开更多
关键词 GEOLOGY HYDROLOGY RADIOACTIVE waste disposal(HLW) rock mass quality joint GEOMETRIC features physical/mechanical properties
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Estimation of Fracture Geometry Parameters and Characterization of Rock Mass Structure for the Beishan Area,China 被引量:1
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作者 WEI Xiang GUO Ying +4 位作者 cheng hanlie WEI Jianfei ZHANG Linlin HUO Liang HOU Zhenkun 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2020年第5期1381-1392,共12页
The accurate estimation of fracture geometry parameters and the characterization of rock mass structure are two important topics in the geological disposal system of high-level radioactive waste(HLW).The Beishan area,... The accurate estimation of fracture geometry parameters and the characterization of rock mass structure are two important topics in the geological disposal system of high-level radioactive waste(HLW).The Beishan area,as the current preselected area for China’s HLW disposal,has three subareas considered to be the key survey area at the stage of site selection.In this paper,a comprehensive survey method conducted on the outcrop is developed to estimate fracture geometry parameters.Results show that fracture occurrence obeys a Fisher distribution,fracture trace length obeys a normal distribution,and the distribution of spacing obeys a negative exponential distribution.An evaluation index,Rock Mass Structure Rating(RMSR),is proposed to characterize rock mass structure for the three subareas.The results show that the Xinchang area is more suitable to act as China’s HLW disposal repository site.At the same time,the index can also be applied to characterize surface rock mass structure and rock mass integrity at the site selection phase of HLW disposal. 展开更多
关键词 fracture geometry parameters rock mass structure high-level radioactive waste disposal RMSR Beishan area
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