High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production meth...High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.展开更多
针对车载网络中能源交易过程不可信和不透明等安全和隐私保护问题,提出了一种基于联盟区块链技术的车载网络能源交易方法。通过分析车载网络中路侧单元(Road Side Unit,RSU)与车辆点对点的传输方式,实现车辆节点之间形成联盟共识区块,...针对车载网络中能源交易过程不可信和不透明等安全和隐私保护问题,提出了一种基于联盟区块链技术的车载网络能源交易方法。通过分析车载网络中路侧单元(Road Side Unit,RSU)与车辆点对点的传输方式,实现车辆节点之间形成联盟共识区块,进而彼此间交易能量,以实现最大化能源交易任务收益,通过鼓励车辆参与能源交易,以智能合约分析车辆参与车载网络能源交易的意愿,满足需放电能源需求,提高能源效率,实现安全、可信的车载网络能源交易过程。展开更多
The Late Cretaceous tectonic upheaval was an important event during the evolution of the Qaidam Basin, resulting in the omission of the Upper Cretaceous in the whole basin and unconformities between the Paleogene sequ...The Late Cretaceous tectonic upheaval was an important event during the evolution of the Qaidam Basin, resulting in the omission of the Upper Cretaceous in the whole basin and unconformities between the Paleogene sequence and pre-K2 strata. Inte-grating geological and geophysical data, two different groups of Late Cretaceous faults were recognized in the study area, one group consisting of E-W extending strike-slip faults (e.g., the Maxian and Yema-Jinan faults in the Mahai area, which caused an E-W omission zone of Mesozoic), while the other one has NW-SE thrust faults, resulting in NW-SE fold-and-thrust belts. Considering the different strikes and scale of these two groups, a simple-shear model has been employed to explain this structural phenomenon. The NW-SE thrust faults were thought to be subsidiary to the E-W strike-slip faults. Putting this into the framework of the Cretaceous paleogeographic environment of central Asia, it is inferred that this tectonic event of the Qaidam Basin is a response to the continuous northward drifting of the India plate.展开更多
基金Natural Science Foundation of Shanghai(24ZR1400800)he Natural Science Foundation of China(U23A20685,52073058,91963204)+1 种基金the National Key R&D Program of China(2021YFB3701400)Shanghai Sailing Program(23YF1400200)。
文摘High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.
文摘针对车载网络中能源交易过程不可信和不透明等安全和隐私保护问题,提出了一种基于联盟区块链技术的车载网络能源交易方法。通过分析车载网络中路侧单元(Road Side Unit,RSU)与车辆点对点的传输方式,实现车辆节点之间形成联盟共识区块,进而彼此间交易能量,以实现最大化能源交易任务收益,通过鼓励车辆参与能源交易,以智能合约分析车辆参与车载网络能源交易的意愿,满足需放电能源需求,提高能源效率,实现安全、可信的车载网络能源交易过程。
文摘The Late Cretaceous tectonic upheaval was an important event during the evolution of the Qaidam Basin, resulting in the omission of the Upper Cretaceous in the whole basin and unconformities between the Paleogene sequence and pre-K2 strata. Inte-grating geological and geophysical data, two different groups of Late Cretaceous faults were recognized in the study area, one group consisting of E-W extending strike-slip faults (e.g., the Maxian and Yema-Jinan faults in the Mahai area, which caused an E-W omission zone of Mesozoic), while the other one has NW-SE thrust faults, resulting in NW-SE fold-and-thrust belts. Considering the different strikes and scale of these two groups, a simple-shear model has been employed to explain this structural phenomenon. The NW-SE thrust faults were thought to be subsidiary to the E-W strike-slip faults. Putting this into the framework of the Cretaceous paleogeographic environment of central Asia, it is inferred that this tectonic event of the Qaidam Basin is a response to the continuous northward drifting of the India plate.
