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利用红外成像和纳米压痕测试技术研究热处理落叶松管胞性能 被引量:8
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作者 王喆 孙柏玲 +1 位作者 柴宇博 刘君良 《林业工程学报》 CSCD 北大核心 2022年第3期67-72,共6页
以我国主要用材树种日本落叶松木材为研究对象,采用物理改性方法真空热处理技术对其材质进行改良。利用场发射扫描电子显微镜和傅里叶变换红外成像显微镜研究不同热处理条件(160~240℃温度范围,处理4 h)下落叶松木材晚材管胞细胞壁形态... 以我国主要用材树种日本落叶松木材为研究对象,采用物理改性方法真空热处理技术对其材质进行改良。利用场发射扫描电子显微镜和傅里叶变换红外成像显微镜研究不同热处理条件(160~240℃温度范围,处理4 h)下落叶松木材晚材管胞细胞壁形态、化学组分结构和分布的变化规律,并结合纳米压痕测试系统研究热处理木材细胞壁力学性能变化趋势。结果表明:木材热处理过程中,随着热处理温度的升高,晚材管胞细胞壁出现裂纹并增加;半纤维素发生降解,细胞壁红外成像中半纤维素相对高浓度分布区域逐渐减少,木质素高浓度分布区域呈现先增加后降低的趋势,表明该过程中木质素发生了热解并进行了重新分布。木材细胞壁压痕弹性模量和硬度随着真空热处理温度的增加呈先增大后降低的趋势,其中当热处理温度为200℃时,压痕弹性模量和硬度相比素材分别增大54.57%和45.69%,达到最大值,该变化规律与木材细胞壁中木质素分布变化趋势相吻合。以上研究结果有助于深入理解真空热处理木材性能的变化,为真空热处理改性木材工艺优化提供理论依据。 展开更多
关键词 日本落叶松 晚材管胞 真空热处理 红外成像 纳米压痕
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苯酚-三聚氰胺脲醛树脂浸渍改性人工林杨木的性能分析 被引量:6
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作者 柴宇博 唐召群 刘君良 《中国人造板》 2019年第12期15-18,共4页
为提高人工林杨木的物理、力学、阻燃及防腐性能,采用不同浓度的苯酚-三聚氰胺脲醛(PMUF)树脂浸渍处理人工林杨木,并对改性材的各项性能进行评价。结果表明:相比未处理材,经过不同浓度PMUF树脂浸渍处理后的改性材,其密度、抗胀率、抗弯... 为提高人工林杨木的物理、力学、阻燃及防腐性能,采用不同浓度的苯酚-三聚氰胺脲醛(PMUF)树脂浸渍处理人工林杨木,并对改性材的各项性能进行评价。结果表明:相比未处理材,经过不同浓度PMUF树脂浸渍处理后的改性材,其密度、抗胀率、抗弯弹性模量、抗弯强度、氧指数及耐腐性均随PMUF树脂浓度的增大而提高,吸湿率随PMUF树脂浓度的增大而降低,游离甲醛释放量均≤0.3 mg/L。 展开更多
关键词 杨木 苯酚-三聚氰胺脲醛树脂 浸渍改性
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硅溶胶与GU/GMU树脂复合改性橡胶木的性能 被引量:2
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作者 平立娟 柴宇博 +1 位作者 刘君良 孙柏玲 《林业科学》 EI CAS CSCD 北大核心 2021年第10期111-119,共9页
【目的】采用硅溶胶与乙二醛-尿素(GU)/乙二醛-三聚氰胺-尿素(GMU)树脂混合溶液浸渍处理橡胶木,探究改性剂种类和浓度对橡胶木物理力学性能和热稳定性的影响,以扩大橡胶木的应用范围,提升橡胶木的附加值。【方法】以乙二醛、三聚氰胺和... 【目的】采用硅溶胶与乙二醛-尿素(GU)/乙二醛-三聚氰胺-尿素(GMU)树脂混合溶液浸渍处理橡胶木,探究改性剂种类和浓度对橡胶木物理力学性能和热稳定性的影响,以扩大橡胶木的应用范围,提升橡胶木的附加值。【方法】以乙二醛、三聚氰胺和尿素为主要原料,分别合成GU、GMU树脂,与硅溶胶以不同比例配制成均一稳定的水溶性混合溶液。采用混合溶液浸渍处理橡胶木,并与硅溶胶改性橡胶木的增重率、尺寸稳定性和力学性能进行比较,通过热重(TG)、傅里叶变换红外光谱(FTIR)和场发射扫描电子显微镜-X射线能谱仪(FESEM-EDS)等手段,分析改性材的热性能、化学分子结构变化和微观构造。【结果】1)混合溶液改性材的增重率和尺寸稳定性随改性剂浓度增加而增大,当改性剂浓度相同时,S-GMU改性材的增重率和尺寸稳定性优于S-GU改性材;S-20%GMU改性材的增重率(28.32%)和抗胀缩率(42.02%)最大,相比S-20%GU改性材分别提高16.98%和14.40%。2)混合溶液改性材的抗弯强度随增重率增大而增加,S-20%GMU改性材的抗弯强度(114.96 MPa)相比S-20%GU改性材提高11.97%,弹性模量变化不大。3)S-GMU混合溶液起到稳定木材残留物的作用,S-GMU改性材热稳定性增强,S-20%GMU改性材残灰率分别是素材、硅溶胶改性材和S-20%GU改性材的5.25、1.20和1.12倍。4)S-GMU改性材在470 cm^(-1)和1110 cm^(-1)附近出现Si—O—Si键和C—O—C醚键,说明硅溶胶和GMU树脂能够进入木材;同时,改性材在1656 cm^(-1)和1510 cm^(-1)处波峰强度下降,说明改性材的木质素和碳水化合物发生一定程度降解,其中S-20%GMU改性材降解程度最低。5)改性剂成功渗透并沉积在木材细胞腔和细胞壁中,S-20%GMU改性材中Si元素较多,Si元素与混合溶液分布均匀,改性剂浸渍效果更好;S-20%GMU改性材中N元素含量增多,说明GMU树脂能够进入木材。【结论】1)硅溶胶与GU/GMU树脂混合溶液浸渍处理橡胶木的增重率、尺寸稳定性和力学性能均优于硅溶胶改性材,且相同质量分数S-GMU改性材的性能优于S-GU改性材;2)硅溶胶和GMU树脂成功渗透并沉积在木材细胞腔和细胞壁中,S-GMU混合溶液起到稳定木材残留物的作用,S-GMU改性材热稳定性增强。 展开更多
关键词 橡胶木 改性 硅溶胶 GU树脂 GMU树脂
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Study on Physical and Mechanical Properties of Poplar Modified by Phenol-formaldehyde Resin
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作者 chai yubo LIU Huanrong +2 位作者 LIU Juniang LI Longzhe TANG Deguo 《Chinese Forestry Science and Technology》 2008年第1期82-87,共6页
Impregnation method can effectively improve physical and mechanical properties of wood.In this study,plantation poplar lumbers are impregnated by a low molecular weight phenol-formaldehyde resin solution with concentr... Impregnation method can effectively improve physical and mechanical properties of wood.In this study,plantation poplar lumbers are impregnated by a low molecular weight phenol-formaldehyde resin solution with concentration of 30%under vacuum-pressure process,and then dried and machined according to the related standards.The results show that the physical and mechanical properties of poplar can be improved by the treatment,except for toughness.The average density of poplar increases from 0.397 to 0.710 g/cm3,the modulus of elasticity in static bending,the bending strength and the compressive strength parallel to grain of treated specimens increase by 56.71%,112.97%and 87.69%,respectively,compared to the untreated.And the hardness values on radial and tangential sections,and nail holding power as well as abrasion resistance of treated specimens improve by 283.87%,82.78%,71.43%and 22.06%,respectively;while toughness decreases by 48.80%. 展开更多
关键词 phenol-formaldehyde MODIFICATION IMPREGNATION I-72 poplar(Populus xeuramericana) density strength plantion physical mechanical property
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Impact of Drying Methods on Wettability of Populus tomentosa
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作者 ZHOU Yongdong JIANG Xiaomei +3 位作者 LIU Juniang chai yubo WANG Jing WANG Shu 《Chinese Forestry Science and Technology》 2008年第3期56-60,共5页
Plantation poplar is one of the most important resources for wood industry,its utilization field is vast.The wettability of Populus tomentosa with different drying methods was judged by measurement of contact angle us... Plantation poplar is one of the most important resources for wood industry,its utilization field is vast.The wettability of Populus tomentosa with different drying methods was judged by measurement of contact angle using distilled water in this paper.The results showed that the specimens from conventional drying have the biggest contact angle,and the air dried have the smallest contact angle,air dried lumbers have a better wettability than the kiln dried.The changes of contact angle in a period of time showed wettability sequence of lumber with different drying methods:air drying>high temperature drying>conventional drying.The basic property for high value-added plantation poplar lumber products was provided to the wood industry. 展开更多
关键词 air drying conventional drying high temperature drying poplar(Populus tomentosa) contact angle WETTABILITY
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Characteristics of Larch Bark Pyrolysis and Analyses on Liquid Pyrolyzate Components
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作者 YAN Zhen ZHAO Yong +2 位作者 chai yubo LIU Yurong WANG Shu 《Chinese Forestry Science and Technology》 2007年第1期14-18,共5页
This paper studies the characteristics of larch bark pyrolysis and analyzes factors that affect the pyrolysis and the liquid pyrolytic component. The results are as follows: TG curve shows that the pyrolysis can be di... This paper studies the characteristics of larch bark pyrolysis and analyzes factors that affect the pyrolysis and the liquid pyrolytic component. The results are as follows: TG curve shows that the pyrolysis can be divided into three parts: drying process, pyrolytic process, and carbonate and calcinated process. Both the size of grain and the temperature rising rate affect the shape of TG and DTG. Vinegar and sedimentary tar are main components of pyrolyzate products. GC-MS is applied to analyze vinegar. It is shown that the vinegar is a highly complex compound which is composed of phenol and its derivatives (45.620%), organic acid (13.851%), keto derivatives (9.754%), aldehydic derivatives (8.573%), alcoholic derivatives (1.794%), ester and its derivatives (0.205%). 展开更多
关键词 BARK PYROLYSIS VINEGAR LARCH Larix gmelini
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Wettability of Poplar Wood Impregnated by Phenol-formaldehyde Resin
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作者 chai yubo LIU Junliang WANG Ming 《Chinese Forestry Science and Technology》 2009年第2期19-23,共5页
In this study,plantation poplar wood was first impregnated by low molecular weightphenol-formaldehyde(PF)resin solution by vacuum-pressure process.And then the wettability ofsanded and non-sanded radial and tangential... In this study,plantation poplar wood was first impregnated by low molecular weightphenol-formaldehyde(PF)resin solution by vacuum-pressure process.And then the wettability ofsanded and non-sanded radial and tangential sections from un-impregnated and impregnated poplarwood was tested respectively by the measurement of contact angles using different liquids.Finally,thesurface free energy of different samples was estimated by the plot extrapolation method.The resultsshowed that the wettability of wood declined after impregnation with PF resin,but it could be improvedby sanding;and the contact angle decreased with increasing surface free energy.Both wood texture andtesting liquid affected the wettability.The sequence of the three chemical reagents is:diiodomethane(good)>formamide(medium)>distilled water(bad). 展开更多
关键词 IMPREGNATION WETTABILITY contact angle surface free energy
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