期刊文献+
共找到4篇文章
< 1 >
每页显示 20 50 100
Shear strength and permeability in the sliding zone soil of reservoir landslides:Insights into the seepage-shear coupling effect 被引量:1
1
作者 Qianyun Wang Huiming Tang +3 位作者 Pengju An Kun Fang biying zhou Xinping Zhang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第4期2031-2040,共10页
The strength of the sliding zone soil determines the stability of reservoir landslides.Fluctuations in water levels cause a change in the seepage field,which serves as both the external hydrogeological environment and... The strength of the sliding zone soil determines the stability of reservoir landslides.Fluctuations in water levels cause a change in the seepage field,which serves as both the external hydrogeological environment and the internal component of a landslide.Therefore,considering the strength changes of the sliding zone with seepage effects,they correspond with the actual hydrogeological circumstances.To investigate the shear behavior of sliding zone soil under various seepage pressures,24 samples were conducted by a self-developed apparatus to observe the shear strength and measure the permeability coefficients at different deformation stages.After seepage-shear tests,the composition of clay minerals and microscopic structure on the shear surface were analyzed through X-ray and scanning electron microscope(SEM)to understand the coupling effects of seepage on strength.The results revealed that the sliding zone soil exhibited strain-hardening without seepage pressure.However,the introduction of seepage caused a significant reduction in shear strength,resulting in strain-softening characterized by a three-stage process.Long-term seepage action softened clay particles and transported broken particles into effective seepage channels,causing continuous damage to the interior structure and reducing the permeability coefficient.Increased seepage pressure decreased the peak strength by disrupting occlusal and frictional forces between sliding zone soil particles,which carried away more clay particles,contributing to an overhead structure in the soil that raised the permeability coefficient and decreased residual strength.The internal friction angle was less sensitive to variations in seepage pressure than cohesion. 展开更多
关键词 Sliding zone soil Permeability coefficient Shear strength Seepage pressure Reservoir landslides
在线阅读 下载PDF
双齿氮配体螯合五价碘试剂介导的苯酚氧化去芳构化机理的理论研究 被引量:2
2
作者 张丹琪 邵英博 +2 位作者 郑汉良 周碧莹 薛小松 《化学学报》 SCIE CAS CSCD 北大核心 2021年第11期1394-1400,共7页
采用密度泛函理论方法研究了不同配体螯合五价碘试剂介导的苯酚氧化去芳构化反应机理以及配体对试剂活性的影响机制.揭示了双齿氮配体具有双重作用:一方面通过配位螯合作用增强五价碘试剂2-碘酰苯甲酸(2-iodoxybenzoic acid,IBX)的反应... 采用密度泛函理论方法研究了不同配体螯合五价碘试剂介导的苯酚氧化去芳构化反应机理以及配体对试剂活性的影响机制.揭示了双齿氮配体具有双重作用:一方面通过配位螯合作用增强五价碘试剂2-碘酰苯甲酸(2-iodoxybenzoic acid,IBX)的反应活性,另一方面作为碱捕获反应中生成的强酸,避免强酸与邻醌产物发生进一步反应,从而提高反应的总收率.研究结果将增加和深化对配体调控高价碘试剂反应性的认识和理解,为理性设计与开发新配体和反应提供理论依据. 展开更多
关键词 双齿氮配体 五价碘试剂 氧化去芳构化 邻醌 密度泛函理论计算
原文传递
Childbearing or Working?——Impact of Childbirth on Rural Women's Interruption of Off-farm Employment
3
作者 biying zhou 《Asian Agricultural Research》 2018年第4期8-15,共8页
To assess the work interruption information and examine the correlation between childbirth and the off-farm employment interruption of rural women,this article collected 3 820 women's childbirth and employment inf... To assess the work interruption information and examine the correlation between childbirth and the off-farm employment interruption of rural women,this article collected 3 820 women's childbirth and employment information over the past 18 years( 1998-2015),using multivariate regression to explore the impact of female individual,family and employment characteristics on probability of employment interruption and duration of interruption. Results indicated that overall,40% of women got interrupted after childbirth in rural areas and the average duration of interruption was about four years. Human capital factors,such as their work experience,first childbirth age and education experience,influence the probability of employment interruption,but these factors do not extend the duration of interruption for women who got interrupted.It is concluded that increasing the human capital of rural women is helpful to increasing their labor force participation rate after childbirth. 展开更多
关键词 Interruption of employment CHILDBIRTH Off-farm employment
在线阅读 下载PDF
Quantification of the Activation Capabilities of Lewis/Brφnsted Acid for Electrophilic Trifluoromethylthiolating Reagents
4
作者 Huiying Kang biying zhou +2 位作者 Man Li Xiao-Song Xue Jin-Pei Cheng 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2020年第2期130-134,共5页
Summary of main observation and conclusion Electrophilic trifluoromethylthiolation has emerged as an important and efficient methodology for installing the SCF3 moiety onto an array of organic molecules.Due to the low... Summary of main observation and conclusion Electrophilic trifluoromethylthiolation has emerged as an important and efficient methodology for installing the SCF3 moiety onto an array of organic molecules.Due to the low reactivities of trifluoromethylthiolating reagents,these transformations often require activation through an exogenous Lewis/Br0nsted acid.We report herein the quantification of the activation capabilities of Lewis/Br0nsted acids for trifluoromethylthiolating reagents through computing the differenee in trifluoromethylthio cation donor ability(Tt+DA)between the"activated"and"unactivated"reagent.A moderate correlation is found to exist between the activation capability and Lewis acidity. 展开更多
关键词 activation MOIETY DONOR
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部