CONSPECTUS:Organic battery electrode materials are key enablers of different postlithium cell chemistries.As a p-type compound with up to two reversible redox processes at relatively high potentials of 3.5 and 4.1 V v...CONSPECTUS:Organic battery electrode materials are key enablers of different postlithium cell chemistries.As a p-type compound with up to two reversible redox processes at relatively high potentials of 3.5 and 4.1 V vs.Li/Li+,phenothiazine is an excellently suited redox-active group.It can easily be functionalized and incorporated into polymeric structures,a prerequisite to obtain insolubility in liquid battery electrolytes.展开更多
基金supported by a doctoral scholarship from the Cusanuswerk,Bonn(Germany)the German Research Foundation(DFG)under Project ID 390874152(POLiS Cluster of Excellence,EXC 2154)and 441215516(SPP 2248 Polymer-based batteries)by the European Union(ERC,NanOBatt,101088146).
文摘CONSPECTUS:Organic battery electrode materials are key enablers of different postlithium cell chemistries.As a p-type compound with up to two reversible redox processes at relatively high potentials of 3.5 and 4.1 V vs.Li/Li+,phenothiazine is an excellently suited redox-active group.It can easily be functionalized and incorporated into polymeric structures,a prerequisite to obtain insolubility in liquid battery electrolytes.