This review covers recent advances in fabrication of nanomaterials in polymer solutions with emphasis on using the self assembled amphiphilic block copolymers in solution to fabricate organic/inorganic composites with...This review covers recent advances in fabrication of nanomaterials in polymer solutions with emphasis on using the self assembled amphiphilic block copolymers in solution to fabricate organic/inorganic composites with nanoscale modifications. The phase behavior of block copolymers in water and the use of templates to form ordered nanostructures are reviewed in detail. Modern physical techniques for nanoscale characterization are also introduced. The authors suggested that this approach should provide new routes to create materials with interesting morphologies for many different applications.展开更多
Polymeric systems have played an important role as structure-directing agents and in the control of nucleation and growth of crystals.This article reviews the work of our research group in the field of the polymer-ass...Polymeric systems have played an important role as structure-directing agents and in the control of nucleation and growth of crystals.This article reviews the work of our research group in the field of the polymer-assisted crystallization of inorganic materials,mainly focused on the formation of highly ordered,porous molybdenum oxide nanostructures.Different experimental parameters including the influence of poly(ethylene oxide)-containing polymers on the morphology and structure of the products obtained fr...展开更多
基金BC gratefully acknowledges support of this work by the Polymers Program of the National Science Foundation(DMR9984102)by the US Department of Energy(DEFG0286ER45237.O16).
文摘This review covers recent advances in fabrication of nanomaterials in polymer solutions with emphasis on using the self assembled amphiphilic block copolymers in solution to fabricate organic/inorganic composites with nanoscale modifications. The phase behavior of block copolymers in water and the use of templates to form ordered nanostructures are reviewed in detail. Modern physical techniques for nanoscale characterization are also introduced. The authors suggested that this approach should provide new routes to create materials with interesting morphologies for many different applications.
基金support by the Basic Energy Sciences,Department of Energy (DEFG0286ER45237).
文摘Polymeric systems have played an important role as structure-directing agents and in the control of nucleation and growth of crystals.This article reviews the work of our research group in the field of the polymer-assisted crystallization of inorganic materials,mainly focused on the formation of highly ordered,porous molybdenum oxide nanostructures.Different experimental parameters including the influence of poly(ethylene oxide)-containing polymers on the morphology and structure of the products obtained fr...