We describe the mechanical properties of turbostratically graphitized carbon films obtained by carbon laser-patterning(CLaP)and their application as bending or mechanical pressure sensors.Stable conductive carbonized ...We describe the mechanical properties of turbostratically graphitized carbon films obtained by carbon laser-patterning(CLaP)and their application as bending or mechanical pressure sensors.Stable conductive carbonized films were imprinted on a flexible polyethylene terephthalate(PET)substrate by laser-induced carbonization.After initial gentle bending,i.e.training,these spongelike porous films show a quantitative and reversible change in resistance upon bending or application of pressure in normal loading direction.Maximum response values ofΔR/R0=388%upon positive bending(tensile stress)and−22.9%upon negative bending(compression)are implicit for their high sensitivity towards mechanical deformation.Normal mechanical loading in a range between 0 and 500 kPa causes a response betweenΔR/R_(0)=0 and−15%.The reversible increase or decrease in resistance is attributed to compression or tension of the turbostratically graphitized domains,respectively.This mechanism is supported by a detailed microstructural and chemical high-resolution transmission electron microscopic analysis of the cross-section of the laserpatterned carbon.展开更多
基金support from the Fonds der Chemischen Industrie and the Max Planck Society.
文摘We describe the mechanical properties of turbostratically graphitized carbon films obtained by carbon laser-patterning(CLaP)and their application as bending or mechanical pressure sensors.Stable conductive carbonized films were imprinted on a flexible polyethylene terephthalate(PET)substrate by laser-induced carbonization.After initial gentle bending,i.e.training,these spongelike porous films show a quantitative and reversible change in resistance upon bending or application of pressure in normal loading direction.Maximum response values ofΔR/R0=388%upon positive bending(tensile stress)and−22.9%upon negative bending(compression)are implicit for their high sensitivity towards mechanical deformation.Normal mechanical loading in a range between 0 and 500 kPa causes a response betweenΔR/R_(0)=0 and−15%.The reversible increase or decrease in resistance is attributed to compression or tension of the turbostratically graphitized domains,respectively.This mechanism is supported by a detailed microstructural and chemical high-resolution transmission electron microscopic analysis of the cross-section of the laserpatterned carbon.
