The rational synergy of chemical composition and spatial nanostructures of electrode materials play important roles in high-performance energy storage devices.Here,we designed pea-like MoS_(2)@NiS_(1.03)-carbon hollow...The rational synergy of chemical composition and spatial nanostructures of electrode materials play important roles in high-performance energy storage devices.Here,we designed pea-like MoS_(2)@NiS_(1.03)-carbon hollow nanofibers using a simple electrospinning and thermal treatment method.The hierarchical hollow nanofiber is composed of a nitrogen-doped carbon-coated NiS_(1.03) tube wall,in which pea-like uniformly discrete MoS_(2) nanoparticles are enclosed.As a sodium-ion battery electrode material,the MoS_(2)@NiS_(1.03)-carbon hollow nanofibers have abundant diphasic heterointerfaces,a conductive network,and appropriate volume variation-buffering spaces,which can facilitate ion diffusion kinetics,shorten the diffusion path of electrons/ion,and buffer volume expansion during Na^(+)insertion/extraction.It shows outstanding rate capacity and long-cycle performance in a sodium-ion battery.This heterogeneous hollow nanoarchitectures designing enlightens an efficacious strategy to boost the capacity and long-life stability of sodium storage performance of electrode materials.展开更多
Proteus mirabilis is abundant in soil and water,and although it is part of the normal human intestinal flora(along with Klebsiella species and Escherichia coli),it is known to cause serious infections in humans,with a...Proteus mirabilis is abundant in soil and water,and although it is part of the normal human intestinal flora(along with Klebsiella species and Escherichia coli),it is known to cause serious infections in humans,with a fatality rate of 20%-50%[1].Proteus mirabilis is intrinsically resistant to tetracycline,tigecycline,and colistin.The widespread and irregular use of antimicrobial agents,P.mirabilis antimicrobial resistance has mirabilis.They acquire antimicrobial resistance(AMR)by capturing plasmids,transposons,or other mobile elements harboring antimicrobial resistance genes.This mechanism allows the rapid selection and transmission of numerous AMR genes in clinical,veterinary,food production,transportation,and environmental settings.展开更多
In recent years,electrospun nanofibers have attracted great attention for their facile adjustable structure,morphology feature and chemical composition.Especially,significant interest has been devoted to the developme...In recent years,electrospun nanofibers have attracted great attention for their facile adjustable structure,morphology feature and chemical composition.Especially,significant interest has been devoted to the development of electrospun nanofibers with multiscale pores from micropores and mesopores to macropores,owing to their large specific surface area,hierarchical pore structures,abundant active sites and many other unique properties and applications.This review presents an overview on the design strategies,preparation methods,physical properties and applications of electrospun hierarchical porous nanofibers.At first,electrospinning fabrication of nanofibers with different types of pores including micropores,mesopores,macropores and hierarchical pores are introduced.Then the structures,properties of electrospun porous nanofibers and their applications in several important areas,such as catalysis,energy storage,adsorption and separation,heat insulation and flame retardant,sound absorption and wave absorption,sensor and biomedical are summarized.At last,challenges and potential opportunities of electrospun porous nanofibers in the future are highlighted.展开更多
基金financially supported by the National Natural Science Foundation of China(NSFC)(Grant Nos.22175007,21975007,52172080,and 22005012)the National Natural Science Foundation for Outstanding Youth Foundation,the Fundamental Research Funds for the Central Universities,the National Program for Support of Top-notch Young Professionalsthe 111 project(Grant No.B14009).
文摘The rational synergy of chemical composition and spatial nanostructures of electrode materials play important roles in high-performance energy storage devices.Here,we designed pea-like MoS_(2)@NiS_(1.03)-carbon hollow nanofibers using a simple electrospinning and thermal treatment method.The hierarchical hollow nanofiber is composed of a nitrogen-doped carbon-coated NiS_(1.03) tube wall,in which pea-like uniformly discrete MoS_(2) nanoparticles are enclosed.As a sodium-ion battery electrode material,the MoS_(2)@NiS_(1.03)-carbon hollow nanofibers have abundant diphasic heterointerfaces,a conductive network,and appropriate volume variation-buffering spaces,which can facilitate ion diffusion kinetics,shorten the diffusion path of electrons/ion,and buffer volume expansion during Na^(+)insertion/extraction.It shows outstanding rate capacity and long-cycle performance in a sodium-ion battery.This heterogeneous hollow nanoarchitectures designing enlightens an efficacious strategy to boost the capacity and long-life stability of sodium storage performance of electrode materials.
基金the National Key Research and Development Program of China[grant number 2021YFC2302002]for financial support.
文摘Proteus mirabilis is abundant in soil and water,and although it is part of the normal human intestinal flora(along with Klebsiella species and Escherichia coli),it is known to cause serious infections in humans,with a fatality rate of 20%-50%[1].Proteus mirabilis is intrinsically resistant to tetracycline,tigecycline,and colistin.The widespread and irregular use of antimicrobial agents,P.mirabilis antimicrobial resistance has mirabilis.They acquire antimicrobial resistance(AMR)by capturing plasmids,transposons,or other mobile elements harboring antimicrobial resistance genes.This mechanism allows the rapid selection and transmission of numerous AMR genes in clinical,veterinary,food production,transportation,and environmental settings.
基金The authors acknowledge the National Natural Science Foundation of China(NSFC)(Grant nos.22175007,21975007,22105012 and 52172080)State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Donghua University(Grant no.KF2021)+4 种基金National Natural Science Foundation for Outstanding Youth Foundationthe Fundamental Research Funds for the Central Universitiesthe National Program for Support of Top-notch Young Professionalsthe 111 project(Grant no.B14009)the China Postdoctoral Science Foundation Funded Project(Grant no.2020M680004).
文摘In recent years,electrospun nanofibers have attracted great attention for their facile adjustable structure,morphology feature and chemical composition.Especially,significant interest has been devoted to the development of electrospun nanofibers with multiscale pores from micropores and mesopores to macropores,owing to their large specific surface area,hierarchical pore structures,abundant active sites and many other unique properties and applications.This review presents an overview on the design strategies,preparation methods,physical properties and applications of electrospun hierarchical porous nanofibers.At first,electrospinning fabrication of nanofibers with different types of pores including micropores,mesopores,macropores and hierarchical pores are introduced.Then the structures,properties of electrospun porous nanofibers and their applications in several important areas,such as catalysis,energy storage,adsorption and separation,heat insulation and flame retardant,sound absorption and wave absorption,sensor and biomedical are summarized.At last,challenges and potential opportunities of electrospun porous nanofibers in the future are highlighted.
