The detailed kinetics of Fischer-Tropsch synthesis over an industrial Fe/Cu/La/Si catalyst was studied in a continuous spinning basket re- actor under the conditions relevant to industrial operations. Reaction rate eq...The detailed kinetics of Fischer-Tropsch synthesis over an industrial Fe/Cu/La/Si catalyst was studied in a continuous spinning basket re- actor under the conditions relevant to industrial operations. Reaction rate equations were derived on the basis of Langmuir-Hinshelwood- Hougen-Watson type models for Fischer-Tropsch synthesis based on possible reactions sets originated from the carbide, enolic and combined enol/carbide mechanisms. Kinetic model candidates were evaluated by the global optimization of kinetic parameters, which were realized by first minimization of multi-response objective functions with conventional Levenberg-Marquardt method. It was found that an enolic mech- anism based model could produce a good fit of the experimental data. The activation energy for paraffin formation is 95 kJ.mo1-1 which is smaller than that for olefin formation （121 kJ.mol-1）.展开更多
The effect of reduction procedure on catalyst properties, activity and products selectivity of ruthenium-promoted Co/γ-Al2O3 catalyst in Fischer-Tropsch synthesis （FTS） was investigated. Catalyst samples were redu...The effect of reduction procedure on catalyst properties, activity and products selectivity of ruthenium-promoted Co/γ-Al2O3 catalyst in Fischer-Tropsch synthesis （FTS） was investigated. Catalyst samples were reduced with different reduction gas compositions and passivated before being characterized by TPR and XRD techniques. Different activity and product selectivity analyses were also performed. These results showed that the catalyst dispersion, particle size, and the degree of reduction changed with different reduction gas compositions, which were resulted from the water partial pressures in reduction process that give varying degrees of interaction with the support. It has been suggested that the FTS activity of cobalt catalyst was directly dependent on the catalyst reducibility. A reduction gas with a molar ratio of H2Prle = 1 was used to prevent the formation of Co-support compound during catalyst reduction.展开更多
文摘The detailed kinetics of Fischer-Tropsch synthesis over an industrial Fe/Cu/La/Si catalyst was studied in a continuous spinning basket re- actor under the conditions relevant to industrial operations. Reaction rate equations were derived on the basis of Langmuir-Hinshelwood- Hougen-Watson type models for Fischer-Tropsch synthesis based on possible reactions sets originated from the carbide, enolic and combined enol/carbide mechanisms. Kinetic model candidates were evaluated by the global optimization of kinetic parameters, which were realized by first minimization of multi-response objective functions with conventional Levenberg-Marquardt method. It was found that an enolic mech- anism based model could produce a good fit of the experimental data. The activation energy for paraffin formation is 95 kJ.mo1-1 which is smaller than that for olefin formation （121 kJ.mol-1）.
文摘The effect of reduction procedure on catalyst properties, activity and products selectivity of ruthenium-promoted Co/γ-Al2O3 catalyst in Fischer-Tropsch synthesis （FTS） was investigated. Catalyst samples were reduced with different reduction gas compositions and passivated before being characterized by TPR and XRD techniques. Different activity and product selectivity analyses were also performed. These results showed that the catalyst dispersion, particle size, and the degree of reduction changed with different reduction gas compositions, which were resulted from the water partial pressures in reduction process that give varying degrees of interaction with the support. It has been suggested that the FTS activity of cobalt catalyst was directly dependent on the catalyst reducibility. A reduction gas with a molar ratio of H2Prle = 1 was used to prevent the formation of Co-support compound during catalyst reduction.
