A study of the behaviors of air discharge plasma inside a catalyst’s pores is important to understand the plasma catalysis mechanism;however,few articles have reported the generation characteristics of air plasma in ...A study of the behaviors of air discharge plasma inside a catalyst’s pores is important to understand the plasma catalysis mechanism;however,few articles have reported the generation characteristics of air plasma in the pores of catalysts.The production of air microdischarge in a pore was studied by a two-dimensional fluid model,mainly focusing on the effect of pore size and applied voltage.The results show that an increase in the pore size in the range of 20–100μm facilitates the occurrence of microdischarge in the pore.In addition,at an applied voltage of 9 kV,the ionization of air mainly occurs near the topside of the pore when the pore diameter is less than 20μm,leading to a low plasma density in the pore,but the time-averaged plasma density in the pore reaches a maximum value at a 70μm pore diameter.Moreover,the applied voltage also has an important effect on the production of air microdischarge in the pore.The existence of a pore of 80μm diameter on the dielectric has no obvious influence on the plasma density in the pore at 2 kV applied voltage,but the plasma density in the pore begins to sharply rise when the voltage exceeds 3 kV due to the enhanced air ionization at higher applied voltage.The study indicates that microdischarge can be generated in a pore with a size of tens of micrometers,and the microdischarge in porous catalysts will affect the catalytic degradation efficacy of gaseous pollutants.展开更多
Both experimental and simulated studies of microdischarge(MD)are carried out in a dielectric barrier discharge with a pin-to-pin gap of 3.5 mm,ignited by a sinusoidal voltage with a peak voltage of 10 kV and a driving...Both experimental and simulated studies of microdischarge(MD)are carried out in a dielectric barrier discharge with a pin-to-pin gap of 3.5 mm,ignited by a sinusoidal voltage with a peak voltage of 10 kV and a driving frequency of 5 kHz.Statistical results have shown that the probability of the single current pulse in the positive half-period(HP)reaches 73.6%under these conditions.Experimental results show that great luminous intensity is concentrated on the dielectric surface and the tip of the metal electrode.A 1D plasma fluid model is implemented by coupling the species continuity equations,electron energy density equations,Poisson equation,and Helmholtz equations to analyze the MD dynamics on the microscale.The simulated results are in good qualitative agreement with the experimental results.The simulated results show that the MD dynamics can be divided into three phases:the Townsend phase,the streamer propagation phase,and the discharge decay phase.During the streamer propagation phase,the electric field and electron density increase with the streamer propagation from the anode to the cathode,and their maximal values reach 625.48 Td and 2.31×10^(19)m^(-3),as well as 790.13 Td and 3.58×10^(19)m^(-3)in the positive and negative HP,respectively.Furthermore,a transient glow-like discharge is detected around the anode during the same period of streamer propagation.The formation of transient glow-like discharge is attributed to electrons drifting back to the anode,which is driven by the residual voltage in the air gap.展开更多
Dielectric barrier discharge(DBD)plasma excited by a high-frequency alternating-current(AC)power supply is widely employed for the degradation of volatile organic compounds(VOCs).However,the thermal effect generated d...Dielectric barrier discharge(DBD)plasma excited by a high-frequency alternating-current(AC)power supply is widely employed for the degradation of volatile organic compounds(VOCs).However,the thermal effect generated during the discharge process leads to energy waste and low energy utilization efficiency.In this work,an innovative DBD thermally-conducted catalysis(DBD-TCC)system,integrating high-frequency AC-DBD plasma and its generated thermal effects to activate the Co/SBA-15 catalyst,was employed for toluene removal.Specifically,Co/SBA-15 catalysts are closely positioned to the ground electrode of the plasma zone and can be heated and activated by the thermal effect when the voltage exceeds 10 k V.At12.4 k V,the temperature in the catalyst zone reached 261℃ in the DBD-TCC system,resulting in an increase in toluene degradation efficiency of 17%,CO_(2)selectivity of 21.2%,and energy efficiency of 27%,respectively,compared to the DBD system alone.In contrast,the DBD thermally-unconducted catalysis(DBD-TUC)system fails to enhance toluene degradation due to insufficient heat absorption and catalytic activation,highlighting the crucial role of AC-DBD generated heat in the activation of the catalyst.Furthermore,the degradation pathway and mechanism of toluene in the DBD-TCC system were hypothesized.This work is expected to provide an energy-efficient approach for high-frequency AC-DBD plasma removal of VOCs.展开更多
In the present work,pulsed gas–liquid hybrid discharge plasma coupled with graphene/Cd S catalyst was evaluated to eliminate bisphenol A(BPA)in wastewater.The optimization of a series of process parameters was perfor...In the present work,pulsed gas–liquid hybrid discharge plasma coupled with graphene/Cd S catalyst was evaluated to eliminate bisphenol A(BPA)in wastewater.The optimization of a series of process parameters was performed in terms of BPA degradation performance.The experimental results demonstrated that nearly 90%of BPA(20 mg l^(-1))in the synthetic wastewater(p H=7.5,σ=10μS m^(-1))was degraded by the plasma catalytic system over 0.2 g l^(-1)graphene/Cd S at 19k V with a 4 l min^(-1)air flow rate and 10 mm electrode gap within 60 min.The BPA removal rate increased with increasing the discharge voltage and decreasing the initial BPA concentration or solution conductivity.Nevertheless,either too high or too low an air flow rate,electrode gap,catalyst dosage or initial solution p H would lead to a decrease in BPA degradation.Moreover,optical emission spectroscopy was used to gain information on short-lived reactive species formed from the pulsed gas–liquid hybrid discharge plasma system.The results indicated the existence of several highly oxidative free radicals such as·O and·OH.Finally,the activation pathway of O_(3)on the catalyst surface was analyzed by density functional theory.展开更多
Corona discharge suppression for high-voltage direct-current(HVDC)transmission lines at line terminals such as converter stations is a subject that requires attention.In this paper,a method based on a conductor covere...Corona discharge suppression for high-voltage direct-current(HVDC)transmission lines at line terminals such as converter stations is a subject that requires attention.In this paper,a method based on a conductor covered with dielectric film is proposed and implemented through a bench-scale setup.Compared with the bare conductor,the corona discharge suppression effect of the dielectric-film-covered conductor under positive polarity is studied from the composite field strength and ion current density using a line-plate experimental device.The influences of film thickness and film material on the corona discharge suppression effect are investigated.The charge accumulation and dissipation characteristics of different film materials are also studied.The results show that the conductor covered with dielectric film has excellent ability to inhibit corona discharge.The ground-level composite field strength of the conductor covered with dielectric film is lower than its nominal field strength,and its ion current density is at the nA m^(−2) level.The corona threshold voltage can be promoted by increasing the film thickness,but the ability to inhibit corona discharge becomes weak.The larger the surface electric field strength,the more charge accumulated,but the faster the charge dissipation rate.Compared with polyvinyl chloride film,cross-linked polyethylene film has stronger charge accumulation ability and slower charge dissipation rate,which can better restrain the corona discharge of HVDC transmission lines.展开更多
The mechanisms of streamer generation and propagation in double-sided pulsed surface dielectric barrier discharge(SDBD)on both sides have been analyzed and investigated by experiment and numerical simulation.The fully...The mechanisms of streamer generation and propagation in double-sided pulsed surface dielectric barrier discharge(SDBD)on both sides have been analyzed and investigated by experiment and numerical simulation.The fully exposed asymmetric SDBD has two discharge processes located on the high voltage electrode(HVE)side and the ground electrode(GE)side.Discharge images of the HVE side and GE side are taken by a digital camera under continuous pulse and ICCD(Intensified Charge Coupled Device)is utilized to diagnose the generation and propagation of streamers in single pulse discharge.In order to understand the physical mechanisms of streamer evolution more deeply,we establish a 2D simulation model and analyze it from the aspects of electron density,ion density,reduced electric field and electron impact ionization source term.The results show that the primary and secondary discharges on the HVE side and the GE side of the double-sided SDBD are composed of positive streamer and negative streamer,respectively.On the HVE side,the accumulation of positive charges on the dielectric surface causes the direction of the electric field to reverse,which is the principal factor for the polarity reversal of the streamer.On the GE side,both the negative charges accumulated on the dielectric surface and the falling voltage are the key factors for the streamer polarity switch.展开更多
The streamer dynamics and charge self-erasing of two counter-propagating plasmas generated by repetitively pulsed surface dielectric barrier discharge are investigated using electrical and optical diagnosis,and a two-...The streamer dynamics and charge self-erasing of two counter-propagating plasmas generated by repetitively pulsed surface dielectric barrier discharge are investigated using electrical and optical diagnosis,and a two-dimensional fluid model.Three distinct discharge phases of primary,transitional and secondary streamers are identified in a single-pulse discharge through the time-resolved plasma images.Moreover,a merging phenomenon of the two opposing primary streamers is observed at the middle position of the discharge gap.Compared to the first pulse,a low streamer propagation velocity of the primary streamer is measured during the subsequent discharge process due to the limitation of residual surface charges left by the previous discharge.No significant dif-ferences of the transferred charge and the deposited energy are obtained in the sequential pulses at a discharge gap of 9 mm.Numerical simulations show that a reduction for the plasma intensity of the approached two primary streamers is attributed by the accumu-lated charge on the dielectric surface and gathered positive charges in the streamer head.Numerical and experimental studies indicate that the residual charges can be erased by the secondary streamer through the drifted electrons,namely that a phenomenon of charge self-erasing can be realized in the individual pulse.展开更多
A dual-frequency(DF)dielectric barrier discharge,excited by the superposition of a 50 Hz low frequency(LF)and a 5000 Hz intermediate frequency(IF),is proposed to enhance discharge.The effect of the LF voltage componen...A dual-frequency(DF)dielectric barrier discharge,excited by the superposition of a 50 Hz low frequency(LF)and a 5000 Hz intermediate frequency(IF),is proposed to enhance discharge.The effect of the LF voltage component on the breakdown behaviour of the DF discharge during different periods has been studied both experimentally and numerically.The number of high-current pulses rises as the LF voltage increases.The statistical analysis shows that the number of the current pulse amplitude above 80 mA in the DF discharge reaches nearly 6 times that in the IF discharge.Additionally,the total discharge energy in the DF discharge is significantly higher than that in the IF discharge.The simulation re-produces the temporal variation of the breakdown behaviours in the DF discharge.The simulated results reveal that the maximal electric field strength of the breakdown process is greater in the DF discharge compared to the IF discharge during a half-period of DF.Finally,the comparison between the IF and DF discharges exhibits that the LF voltage regulates the accumulation of residual charged species on the dielectric surface after the breakdown by modulating the residual voltage between the air gap.展开更多
基金National Natural Science Foundation of China(Nos.51977024 and 21577011).
文摘A study of the behaviors of air discharge plasma inside a catalyst’s pores is important to understand the plasma catalysis mechanism;however,few articles have reported the generation characteristics of air plasma in the pores of catalysts.The production of air microdischarge in a pore was studied by a two-dimensional fluid model,mainly focusing on the effect of pore size and applied voltage.The results show that an increase in the pore size in the range of 20–100μm facilitates the occurrence of microdischarge in the pore.In addition,at an applied voltage of 9 kV,the ionization of air mainly occurs near the topside of the pore when the pore diameter is less than 20μm,leading to a low plasma density in the pore,but the time-averaged plasma density in the pore reaches a maximum value at a 70μm pore diameter.Moreover,the applied voltage also has an important effect on the production of air microdischarge in the pore.The existence of a pore of 80μm diameter on the dielectric has no obvious influence on the plasma density in the pore at 2 kV applied voltage,but the plasma density in the pore begins to sharply rise when the voltage exceeds 3 kV due to the enhanced air ionization at higher applied voltage.The study indicates that microdischarge can be generated in a pore with a size of tens of micrometers,and the microdischarge in porous catalysts will affect the catalytic degradation efficacy of gaseous pollutants.
基金supported by National Natural Science Foundation of China (Nos. 51877027 and 51877028)financially supported by the Fundamental Research Funds for the Central Universities (No. DUT20ZD202)+1 种基金the Science and Technology Development Fund of Xinjiang Production and Construction (No. 2019BC009)the Dalian High-Level Talents Innovation and Entrepreneurship Project (No. 2018RQ28)
文摘Both experimental and simulated studies of microdischarge(MD)are carried out in a dielectric barrier discharge with a pin-to-pin gap of 3.5 mm,ignited by a sinusoidal voltage with a peak voltage of 10 kV and a driving frequency of 5 kHz.Statistical results have shown that the probability of the single current pulse in the positive half-period(HP)reaches 73.6%under these conditions.Experimental results show that great luminous intensity is concentrated on the dielectric surface and the tip of the metal electrode.A 1D plasma fluid model is implemented by coupling the species continuity equations,electron energy density equations,Poisson equation,and Helmholtz equations to analyze the MD dynamics on the microscale.The simulated results are in good qualitative agreement with the experimental results.The simulated results show that the MD dynamics can be divided into three phases:the Townsend phase,the streamer propagation phase,and the discharge decay phase.During the streamer propagation phase,the electric field and electron density increase with the streamer propagation from the anode to the cathode,and their maximal values reach 625.48 Td and 2.31×10^(19)m^(-3),as well as 790.13 Td and 3.58×10^(19)m^(-3)in the positive and negative HP,respectively.Furthermore,a transient glow-like discharge is detected around the anode during the same period of streamer propagation.The formation of transient glow-like discharge is attributed to electrons drifting back to the anode,which is driven by the residual voltage in the air gap.
基金supported by National Natural Science Foundation of China(No.52177130)the Key Projects for Industrial Prospects and Core Technology Research in Suzhou City(No.SYC2022029)。
文摘Dielectric barrier discharge(DBD)plasma excited by a high-frequency alternating-current(AC)power supply is widely employed for the degradation of volatile organic compounds(VOCs).However,the thermal effect generated during the discharge process leads to energy waste and low energy utilization efficiency.In this work,an innovative DBD thermally-conducted catalysis(DBD-TCC)system,integrating high-frequency AC-DBD plasma and its generated thermal effects to activate the Co/SBA-15 catalyst,was employed for toluene removal.Specifically,Co/SBA-15 catalysts are closely positioned to the ground electrode of the plasma zone and can be heated and activated by the thermal effect when the voltage exceeds 10 k V.At12.4 k V,the temperature in the catalyst zone reached 261℃ in the DBD-TCC system,resulting in an increase in toluene degradation efficiency of 17%,CO_(2)selectivity of 21.2%,and energy efficiency of 27%,respectively,compared to the DBD system alone.In contrast,the DBD thermally-unconducted catalysis(DBD-TUC)system fails to enhance toluene degradation due to insufficient heat absorption and catalytic activation,highlighting the crucial role of AC-DBD generated heat in the activation of the catalyst.Furthermore,the degradation pathway and mechanism of toluene in the DBD-TCC system were hypothesized.This work is expected to provide an energy-efficient approach for high-frequency AC-DBD plasma removal of VOCs.
基金supported by the Open Fund for State Environmental Protection Key Laboratory of Synergetic Control and Joint Remediation for Soil&Water Pollution(No.GHBK-2020-006)National Natural Science Foundation of China(No.21876070)。
文摘In the present work,pulsed gas–liquid hybrid discharge plasma coupled with graphene/Cd S catalyst was evaluated to eliminate bisphenol A(BPA)in wastewater.The optimization of a series of process parameters was performed in terms of BPA degradation performance.The experimental results demonstrated that nearly 90%of BPA(20 mg l^(-1))in the synthetic wastewater(p H=7.5,σ=10μS m^(-1))was degraded by the plasma catalytic system over 0.2 g l^(-1)graphene/Cd S at 19k V with a 4 l min^(-1)air flow rate and 10 mm electrode gap within 60 min.The BPA removal rate increased with increasing the discharge voltage and decreasing the initial BPA concentration or solution conductivity.Nevertheless,either too high or too low an air flow rate,electrode gap,catalyst dosage or initial solution p H would lead to a decrease in BPA degradation.Moreover,optical emission spectroscopy was used to gain information on short-lived reactive species formed from the pulsed gas–liquid hybrid discharge plasma system.The results indicated the existence of several highly oxidative free radicals such as·O and·OH.Finally,the activation pathway of O_(3)on the catalyst surface was analyzed by density functional theory.
基金by State Grid Shandong Electric Power Company(52062618001M)。
文摘Corona discharge suppression for high-voltage direct-current(HVDC)transmission lines at line terminals such as converter stations is a subject that requires attention.In this paper,a method based on a conductor covered with dielectric film is proposed and implemented through a bench-scale setup.Compared with the bare conductor,the corona discharge suppression effect of the dielectric-film-covered conductor under positive polarity is studied from the composite field strength and ion current density using a line-plate experimental device.The influences of film thickness and film material on the corona discharge suppression effect are investigated.The charge accumulation and dissipation characteristics of different film materials are also studied.The results show that the conductor covered with dielectric film has excellent ability to inhibit corona discharge.The ground-level composite field strength of the conductor covered with dielectric film is lower than its nominal field strength,and its ion current density is at the nA m^(−2) level.The corona threshold voltage can be promoted by increasing the film thickness,but the ability to inhibit corona discharge becomes weak.The larger the surface electric field strength,the more charge accumulated,but the faster the charge dissipation rate.Compared with polyvinyl chloride film,cross-linked polyethylene film has stronger charge accumulation ability and slower charge dissipation rate,which can better restrain the corona discharge of HVDC transmission lines.
基金supported by National Natural Science Foundation of China(Nos.51877027 and 52107140)Project funded by China Postdoctoral Science Foundation(No.2021M700662)。
文摘The mechanisms of streamer generation and propagation in double-sided pulsed surface dielectric barrier discharge(SDBD)on both sides have been analyzed and investigated by experiment and numerical simulation.The fully exposed asymmetric SDBD has two discharge processes located on the high voltage electrode(HVE)side and the ground electrode(GE)side.Discharge images of the HVE side and GE side are taken by a digital camera under continuous pulse and ICCD(Intensified Charge Coupled Device)is utilized to diagnose the generation and propagation of streamers in single pulse discharge.In order to understand the physical mechanisms of streamer evolution more deeply,we establish a 2D simulation model and analyze it from the aspects of electron density,ion density,reduced electric field and electron impact ionization source term.The results show that the primary and secondary discharges on the HVE side and the GE side of the double-sided SDBD are composed of positive streamer and negative streamer,respectively.On the HVE side,the accumulation of positive charges on the dielectric surface causes the direction of the electric field to reverse,which is the principal factor for the polarity reversal of the streamer.On the GE side,both the negative charges accumulated on the dielectric surface and the falling voltage are the key factors for the streamer polarity switch.
基金National Natural Science Foundation of China,Grant/Award Numbers:51877027,52107140,51877028China Postdoctoral Science Foundation,Grant/Award Number:2021M700662。
文摘The streamer dynamics and charge self-erasing of two counter-propagating plasmas generated by repetitively pulsed surface dielectric barrier discharge are investigated using electrical and optical diagnosis,and a two-dimensional fluid model.Three distinct discharge phases of primary,transitional and secondary streamers are identified in a single-pulse discharge through the time-resolved plasma images.Moreover,a merging phenomenon of the two opposing primary streamers is observed at the middle position of the discharge gap.Compared to the first pulse,a low streamer propagation velocity of the primary streamer is measured during the subsequent discharge process due to the limitation of residual surface charges left by the previous discharge.No significant dif-ferences of the transferred charge and the deposited energy are obtained in the sequential pulses at a discharge gap of 9 mm.Numerical simulations show that a reduction for the plasma intensity of the approached two primary streamers is attributed by the accumu-lated charge on the dielectric surface and gathered positive charges in the streamer head.Numerical and experimental studies indicate that the residual charges can be erased by the secondary streamer through the drifted electrons,namely that a phenomenon of charge self-erasing can be realized in the individual pulse.
基金National Natural Science Foundation of China,Grant/Award Numbers:52177130,52377137,52107140Industrial Prospects and Key Core Technology Projects of Suzhou City,Grant/Award Number:SYC2022029。
文摘A dual-frequency(DF)dielectric barrier discharge,excited by the superposition of a 50 Hz low frequency(LF)and a 5000 Hz intermediate frequency(IF),is proposed to enhance discharge.The effect of the LF voltage component on the breakdown behaviour of the DF discharge during different periods has been studied both experimentally and numerically.The number of high-current pulses rises as the LF voltage increases.The statistical analysis shows that the number of the current pulse amplitude above 80 mA in the DF discharge reaches nearly 6 times that in the IF discharge.Additionally,the total discharge energy in the DF discharge is significantly higher than that in the IF discharge.The simulation re-produces the temporal variation of the breakdown behaviours in the DF discharge.The simulated results reveal that the maximal electric field strength of the breakdown process is greater in the DF discharge compared to the IF discharge during a half-period of DF.Finally,the comparison between the IF and DF discharges exhibits that the LF voltage regulates the accumulation of residual charged species on the dielectric surface after the breakdown by modulating the residual voltage between the air gap.
