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均相和非均相催化微藻脂质提取和酯交换制备生物燃料的研究进展
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作者 Vinoth Kumar Ponnumsamy Hussein E.Al-Hazmi +9 位作者 Sutha Shobana Jeyaprakash Dharmaraja Dipak Ashok Jadhav Rajesh Banu J Grzegorz Piechota Bartłomiej Igliński Vinod Kumar amit bhatnagar Kyu-Jung Chae Gopalakrishnan Kumar 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第4期97-117,共21页
随着化石燃料燃烧导致的二氧化碳排放不断加剧气候变化,且化石燃料储量日益减少,寻求可再生能源已成为一项紧迫的任务.其中,藻类衍生可持续燃料因具有成本优势和可运输性,在解决全球能源危机方面展现出广阔前景,备受关注.利用化学转化... 随着化石燃料燃烧导致的二氧化碳排放不断加剧气候变化,且化石燃料储量日益减少,寻求可再生能源已成为一项紧迫的任务.其中,藻类衍生可持续燃料因具有成本优势和可运输性,在解决全球能源危机方面展现出广阔前景,备受关注.利用化学转化技术从微藻中提取脂质,并通过酯交换反应可以将其转化为脂肪酸甲酯,是生产绿色生物燃料的有效途径.这一过程涉及游离脂肪酸、磷脂和甘油三酯的提取,并且生产过程能耗低,成为满足日益增长的能源需求的一种理想解决方案.本文综述了微藻脂质提取和酯交换制备生物燃料的相关研究进展.首先,介绍了微藻脂质的提取方法,包括溶剂提取法、索氏提取法、布利格和戴耶法、超临界二氧化碳提取以及离子液体溶剂法等,并分析了各方法的优缺点.随后,重点阐述了酯交换技术在微藻脂质转化中的应用,包括酸碱催化、酶催化以及原位酯交换反应等,并探讨了这些技术的反应机理、催化剂选择、反应器设计以及生物油生产工艺等方面的研究进展.通过综述上述研究进展,为微藻脂质的生产和应用提供了理论指导.研究表明,通过优化催化剂种类、反应条件以及提取方法,可以有效提高微藻脂质的转化效率和生物油品质.同时,本文也指出了当前微藻脂质生产中面临的挑战,如微藻栽培和生长条件优化、高效转化技术的开发等.随着可持续能源日益受到重视,微藻脂质作为一种可再生能源具有巨大的发展潜力.未来研究应进一步关注微藻的规模化栽培、生长条件优化以及高效转化技术的研发,以提高微藻脂质的产量和品质.同时,应进一步推动和实现微藻生物燃料的实际应用,从而为应对气候变化和能源危机提供有效的解决方案. 展开更多
关键词 微藻 脂质提取 酯交换 催化 酶催化 原位技术
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Integrated microalgae culture with food processing waste for wastewater remediation and enhanced biomass productivity 被引量:1
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作者 Angela Paul Peter Kit Wayne Chew +7 位作者 Apurav Krishna Koyande Heli Siti Halimatul Munawaroh amit bhatnagar Yang Tao Chihe Sun Fubao Sun Zengling Ma Pau Loke Show 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第2期636-643,共8页
Waste generation from food manufacturing facilities poses a serious hazard like environmental degradation, water pollution, and land pollution due to its high nutrient composition. Specifically, solid waste(powder) di... Waste generation from food manufacturing facilities poses a serious hazard like environmental degradation, water pollution, and land pollution due to its high nutrient composition. Specifically, solid waste(powder) disposal requires additional energy sources in terms of scientific treatment, structured collection, and disposal packaging according to the safety regulation. Thus, this research discusses the viewpoint of integrating food processing waste as an organic carbon source with BG-11 medium for Chlorella vulgaris(FSP-E) growth. The food processing waste powders investigated in this study were obtained from milk, and biscuit manufacturing facilities. The culture medium was modified by combining both BG-11 and food processing waste powders to identify the optimal algal growth and biochemical content.Compared to the microalgae grown in BG-11 alone(IBG), the combination of biscuit waste and IBG produced higher biomass concentration(44%), with increased lipid(11%), protein(20%), and carbohydrate(57%) contents. Chlorella vulgaris was able to uptake nutrients from the culture medium with combination of food processing waste and IBG thus enhancing its growth. The results obtained also indicate that an integrated culture system using food processing waste and synthetic sources can generate energy out of waste by improving the bio-composition of the microalgae biomass. 展开更多
关键词 Medium contamination Food processing Waste powder Organic medium Waste remediation
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Insights into simultaneous adsorption and oxidation of antimonite[Sb(III)]by crawfish shell-derived biochar:spectroscopic investigation and theoretical calculations 被引量:1
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作者 Hanbo Chen Yurong Gao +12 位作者 Jianhong Li Chenghua Sun Binoy Sarkar amit bhatnagar Nanthi Bolan Xing Yang Jun Meng Zhongzhen Liu Hong Hou Jonathan WCWong Deyi Hou Wenfu Chen Hailong Wang 《Biochar》 SCIE 2022年第1期561-576,共16页
Removal of antimonite[Sb(Ⅲ)]from the aquatic environment and reducing its biotoxicity is urgently needed to safeguard environmental and human health.Herein,crawfish shell-derived biochars(CSB),pyrolyzed at 350,500,an... Removal of antimonite[Sb(Ⅲ)]from the aquatic environment and reducing its biotoxicity is urgently needed to safeguard environmental and human health.Herein,crawfish shell-derived biochars(CSB),pyrolyzed at 350,500,and 650℃,were used to remediate Sb(Ⅲ)in aqueous solutions.The adsorption data best fitted to the pseudo-second-order kinetic and Langmuir isotherm models.Biochar produced at 350℃(CSB350)showed the highest adsorption capacity(27.7 mg g^(−1)),and the maximum 78%oxidative conversion of Sb(Ⅲ)to Sb(V).The adsorption results complemented with infrared(FTIR),X-ray photoelectron(XPS),and near-edge X-ray absorption fine structure(NEXAFS)spectroscopy analyses indicated that the adsorption of Sb(Ⅲ)on CSB involved electrostatic interaction,surface complexation with oxygen-containing functional groups(C=O,O=C-O),π-πcoordination with aromatic C=C and C-H groups,and H-bonding with-OH group.Density functional theory calculations verified that surface complexation was the most dominant adsorption mechanism,whilstπ-πcoordination and H-bonding played a secondary role.Furthermore,electron spin resonance(ESR)and mediated electrochemical reduction/oxidation(MER/MEO)analyses confirmed that Sb(Ⅲ)oxidation at the biochar surface was governed by persistent free radicals(PFRs)(•O_(2)^(−)and•OH)and the electron donating/accepting capacity(EDC/EAC)of biochar.The abundance of preferable surface functional groups,high concentration of PFRs,and high EDC conferred CSB350 the property of an optimal adsorbent/oxidant for Sb(Ⅲ)removal from water.The encouraging results of this study call for future trials to apply suitable biochar for removing Sb(Ⅲ)from wastewater at pilot scale and optimize the process. 展开更多
关键词 SORPTION Heavy metal SYNCHROTRON Density functional theory Contaminated water
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Herbal tea formulation using different flavoured herbs with dried corn silk powder and its sensory and phytochemical analysis
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作者 Akanksha Singh Rita Singh Raghuvanshi amit bhatnagar 《Systems Microbiology and Biomanufacturing》 2021年第3期336-343,共8页
The aim of this study was to use dried corn silk powder variety of VL Baby corn-1 for formulation of flavoured herbal tea with different combination of Thyme(Trachyspermum ammi),Clove(Syzygium aromaticum),Cinnamon pow... The aim of this study was to use dried corn silk powder variety of VL Baby corn-1 for formulation of flavoured herbal tea with different combination of Thyme(Trachyspermum ammi),Clove(Syzygium aromaticum),Cinnamon powder(Cinnamomum verum),Timur(Zanthoxylum alatum),Tulsi(Holy basil)(Ocimum tenuiflorum),Gandraini(Achillea millefolium),Lemon grass(Cymbopogon citratus),Blend(Clove+Timur+Gandraini),and one only corn silk without any other herbs and to know antioxidant properties of developed tea.Result of sensory evaluation experiment showed that all combinations were liked moderately.Lemon grass flavour followed by cinnamon and clove blend obtained highest score.Total phenolic content,total flavonoid content,DPPH free radical scavenging activity and total antioxidant activity for all flavour are analyzed and reported.Results on DPPH free radical scavenging activity indicated that corn silk tea had 81.215±0.75μg/mL whereas blend with Timur had significant highest value and Thyme blend had lowest value 64.20±0.40 among all eight different blends with corn silk.The values for total antioxidant capacity blends with Timur(Zanthoxylum alatu)in corn silk showed significantly(P<0.05)highest value and Clove,Timur,Gandraini blends got lowest value. 展开更多
关键词 Herbal tea Corn silk Sensory parameters ANTIOXIDANTS Phenolic content
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