When "dark"is bright:the scarcely explored electrophilic profile of the indolyl core(dark side)continues to inspire developments in organic synthesis by means of new catalytic methodologies.Recent advancemen...When "dark"is bright:the scarcely explored electrophilic profile of the indolyl core(dark side)continues to inspire developments in organic synthesis by means of new catalytic methodologies.Recent advancements in the field enabled molecular diversity and complexity to be effectively realized within heterocyclic chemistry.展开更多
The tandem catalytic functionalization/carboxylation of double as well as triple carbon-carbon bonds with CO_(2) represent an emerging research area in synthetic organic methodology.In particular,the combination of mi...The tandem catalytic functionalization/carboxylation of double as well as triple carbon-carbon bonds with CO_(2) represent an emerging research area in synthetic organic methodology.In particular,the combination of mild reaction conditions,stoichiometric acceptor/donorless conditions(visible light photoredox catalysis)and chiral catalysts contributed to a rapid development of this intriguing research area capable of creating chemical diversity/complexity from readily available unsaturated hydrocarbons and CO2 as a C1-buinding block.The most recent developments in the field have been collected in the present review article and organized,based on the different sets ofπ-systems/intermediates/reactive partners employed(i.e.,nickelalactones,organo-halides)as well as synthetic strategies(i.e.,visible-light photo redox catalysis).展开更多
文摘When "dark"is bright:the scarcely explored electrophilic profile of the indolyl core(dark side)continues to inspire developments in organic synthesis by means of new catalytic methodologies.Recent advancements in the field enabled molecular diversity and complexity to be effectively realized within heterocyclic chemistry.
基金Financial support by the National Key Research and Development Program of China(Grants 2017YFA0204503 and 2017YFA0207800)the National Natural Science Foundation of China(Grants 51903187,21734006 and 21975178)the China Postdoctoral Science Foundation(No.2020M670642)is gratefully acknowledged.
文摘The tandem catalytic functionalization/carboxylation of double as well as triple carbon-carbon bonds with CO_(2) represent an emerging research area in synthetic organic methodology.In particular,the combination of mild reaction conditions,stoichiometric acceptor/donorless conditions(visible light photoredox catalysis)and chiral catalysts contributed to a rapid development of this intriguing research area capable of creating chemical diversity/complexity from readily available unsaturated hydrocarbons and CO2 as a C1-buinding block.The most recent developments in the field have been collected in the present review article and organized,based on the different sets ofπ-systems/intermediates/reactive partners employed(i.e.,nickelalactones,organo-halides)as well as synthetic strategies(i.e.,visible-light photo redox catalysis).
