A decomposed copper based metal-organic framework containing amorphous Cu species was found to be a highly reactive carbon supported catalyst(a-Cu@C).This catalyst is active for reduction,oxidation,and N-arylation rea...A decomposed copper based metal-organic framework containing amorphous Cu species was found to be a highly reactive carbon supported catalyst(a-Cu@C).This catalyst is active for reduction,oxidation,and N-arylation reactions without further tuning or optimization.Higher catalyst turnover numbers for each of these transformations are obtained when comparing a-Cu@C activity to similar Cu-based materials.展开更多
基金supported by start-up funding from Brigham Young Universitysupported by the US Department of Energy[Office of Basic Energy Sciences]DE-FG02-08ER 15997.
文摘A decomposed copper based metal-organic framework containing amorphous Cu species was found to be a highly reactive carbon supported catalyst(a-Cu@C).This catalyst is active for reduction,oxidation,and N-arylation reactions without further tuning or optimization.Higher catalyst turnover numbers for each of these transformations are obtained when comparing a-Cu@C activity to similar Cu-based materials.
