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Mo基复合金属氧化物催化丙烷氧化制丙烯醛 被引量:3
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作者 宋振 陆维敏 +1 位作者 朱艺涵 achim fischer 《石油化工》 EI CAS CSCD 北大核心 2006年第8期730-734,共5页
制备了Mo基复合金属氧化物(MoMxOn,M=C r,Co,Zn,Mn,Nb,Ce)催化剂,评价了不同金属含量的MoMxOn催化剂在不同温度下对丙烷选择性氧化制备丙烯醛反应的催化性能。在所研究的各种MoMxOn催化剂中,MoCo0.1On催化剂在773 K时的催化性能最佳,丙... 制备了Mo基复合金属氧化物(MoMxOn,M=C r,Co,Zn,Mn,Nb,Ce)催化剂,评价了不同金属含量的MoMxOn催化剂在不同温度下对丙烷选择性氧化制备丙烯醛反应的催化性能。在所研究的各种MoMxOn催化剂中,MoCo0.1On催化剂在773 K时的催化性能最佳,丙烯醛的收率为9.3%。Raman光谱和X射线衍射表征结果表明,除MoNbxOn催化剂外,其他各种MoMxOn催化剂中的主要物相是MoO3,说明MoO3可能对催化活性起重要作用。增加Co含量使MoO3衍射峰的相对强度发生改变,可能是引起MoCoxOn催化剂氧化性能下降的原因。 展开更多
关键词 丙烷 丙烯醛 复合金属氧化物 催化剂 选择性氧化
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Stability analysis of a thin-walled cylinder in turning operation using the semi-discretization method 被引量:3
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作者 Arnab Chanda achim fischer +1 位作者 Peter Eberhard Santosha Kumar Dwivedy 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2014年第2期214-222,共9页
In this work, the stability of a flexible thin cylindrical workpiece in turning is analyzed. A process model is derived based on a finite element representation of the workpiece flexibility and a nonlinear cutting for... In this work, the stability of a flexible thin cylindrical workpiece in turning is analyzed. A process model is derived based on a finite element representation of the workpiece flexibility and a nonlinear cutting force law. Repeated cutting of the same surface due to overlapping cuts is modeled with the help of a time delay. The stability of the so obtained system of periodic delay differential equations is then determined using an approximation as a time-discrete system and Floquet theory. The time-discrete system is obtained using the semi-discretization method. The method is implemented to analyze the stability of two different workpiece models of different thicknesses for different tool positions with respect to the jaw end. It is shown that the stability chart depends on the tool position as well as on the thickness. 展开更多
关键词 Machine tools Stability Chatter
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Improving the dynamic stability of a workpiece dominated turning process using an adaptronic tool holder 被引量:1
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作者 achim fischer Peter Eberhard 《Theoretical & Applied Mechanics Letters》 CAS 2013年第1期63-70,共8页
In this contribution, inside turning of a thin-walled cylinder is investigated in simulation. Self-excited vibrations can arise due to repeated cutting of the same surface, that lead to instability.A flexible multibod... In this contribution, inside turning of a thin-walled cylinder is investigated in simulation. Self-excited vibrations can arise due to repeated cutting of the same surface, that lead to instability.A flexible multibody system model of the system is the basis for a subsequent analysis of the stability of the process. Stability analysis is done using an approximation as a time-discrete system via the semi-discretization method. An adaptronic turning chisel comprising a piezo actuator and sensors is then used in combination with different control concepts to improve the stability of the process. The effectiveness of the different strategies is compared based on the influence on the stability charts. A classic H∞ controller based on a model of the coupled system of workpiece and tool can only yield some improvements, when an additional measurement of the workpiece displacement is added. Incorporating knowledge on the cutting process coupling workpiece and tool using a gain scheduled H∞ controller allows further improvements. However, robustness with respect to model uncertainties, notably concerning the force law, remains an issue. C 2013 The Chinese Society of Theoretical and Applie-d Mechanics. [doi:10.1063/2.1301308] 展开更多
关键词 multibody dynamics vibrations STABILITY feedback control
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A high-order full-discretization method using Hermite interpolation for periodic time-delayed differential equations
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作者 Yilong Liu achim fischer +1 位作者 Peter Eberhard Baohai Wu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2015年第3期406-415,共10页
A high-order full-discretization method (FDM) using Hermite interpolation (HFDM) is proposed and implemented for periodic systems with time delay. Both Lagrange interpolation and Hermite interpolation are used to ... A high-order full-discretization method (FDM) using Hermite interpolation (HFDM) is proposed and implemented for periodic systems with time delay. Both Lagrange interpolation and Hermite interpolation are used to approximate state values and delayed state values in each discretization step. The transition matrix over a single period is determined and used for stability analysis. The proposed method increases the approximation order of the semidiscretization method and the FDM without increasing the computational time. The convergence, precision, and efficiency of the proposed method are investigated using several Mathieu equations and a complex turning model as examples. Comparison shows that the proposed HFDM converges faster and uses less computational time than existing methods. 展开更多
关键词 Full-discretization method Time delay -Stability Chatter
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