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离子交换玻璃中的混合氧化物效应
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作者 贺海燕 G.Berg a.ludwig 《国外建材科技》 1997年第1期39-40,共2页
混合碱效应很多年来已是相当广泛研究的领域。它指出这个效应也在网络修饰离子这一的是非碱元素的玻璃中存在。因此更确切地说这个效应应为混合氧化物效应。这个效应的存在实验上被熔融法生产的混合氧化物玻璃所证实。有很多试图描述这... 混合碱效应很多年来已是相当广泛研究的领域。它指出这个效应也在网络修饰离子这一的是非碱元素的玻璃中存在。因此更确切地说这个效应应为混合氧化物效应。这个效应的存在实验上被熔融法生产的混合氧化物玻璃所证实。有很多试图描述这个效应的理论,例如,这些描述或是定性的或在很多情况下是定量的。直到现在,通过与实验比较。 展开更多
关键词 离子交换玻璃 玻璃 氧化物效应 玻璃结构
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Investigation of effect of electrode polarity on electrochemistry and magnetohydrodynamics using tertiary current distribution in electroslag remelting process 被引量:2
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作者 E.Karimi-Sibaki A.Kharicha +3 位作者 A.Vakhrushev M.Wu a.ludwig J.Bohacek 《Journal of Iron and Steel Research International》 SCIE EI CSCD 2021年第12期1551-1561,共11页
Transport phenomena including the electromagnetic,concentration of ions,flow,and thermal fields in the electroslag remelting(ESR)process made of slag,electrode,air,mold,and melt pool are computed considering tertiary ... Transport phenomena including the electromagnetic,concentration of ions,flow,and thermal fields in the electroslag remelting(ESR)process made of slag,electrode,air,mold,and melt pool are computed considering tertiary current distribution.Nernst-Planck equations are solved in the bulk of slag,and faradaic reactions are regarded at the metal-slag interface.Aiming at exploring electrochemical effects on the behavior of the ESR process,the calculated field structures are compared with those obtained using the classical ohmic approach,namely,primary current distribution whereby variations in concentrations of ions and faradaic reactions are ignored.Also,the influence of the earth magnetic field on magnetohydrodynamics in the melt pool and slag is considered.The impact of the polarity of electrode,whether positive,also known as direct current reverse polarity(DCRP),or negative,as known as direct current straight polarity(DCSP),on the transport of oxygen to the ingot of ESR is investigated.The obtained modeling results enabled us to explain the experimental observation of higher oxygen content in DCSP than that of DCRP operated ESR process. 展开更多
关键词 Electroslag remelting ELECTROCHEMISTRY Calcium fluoride Calcium oxide Ion transport Electro-migration
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Simulation of cooling channel rheocasting process of A356 aluminum alloy using three-phase volume averaging model 被引量:1
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作者 T.Wang B.Pustal +4 位作者 M.Abondano T.Grimmig A.Bührig-Polaczek M.Wu a.ludwig 《中国有色金属学会会刊:英文版》 EI CSCD 2005年第2期389-394,共6页
The cooling channel process is a rehocasting method by which the prematerial with globular microstructure can be produced to fit the thixocasting process.A three-phase model based on volume averaging approach is propo... The cooling channel process is a rehocasting method by which the prematerial with globular microstructure can be produced to fit the thixocasting process.A three-phase model based on volume averaging approach is proposed to simulate the cooling channel process of A356 Aluminum alloy.The three phases are liquid,solid and air respectively and treated as separated and interacting continua,sharing a single pressure field.The mass,momentum,enthalpy transport equations for each phase are solved.The developed model can predict the evolution of liquid,solid and air fraction as well as the distribution of grain density and grain size.The effect of pouring temperature on the grain density,grain size and solid fraction is analyzed in detail. 展开更多
关键词 A356 alloy MODELING cooling channel THREE-PHASE SEMI-SOLID
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Role of fragmentation in as-cast structure:numerical study and experimental validation
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作者 Yong-jian Zheng Meng-huai Wu +1 位作者 A.Kharicha a.ludwig 《China Foundry》 SCIE 2017年第5期321-326,共6页
A volume average solidification model is extended to incorporate fragmentation as the source of equiaxed crystals during mixed columnar-equiaxed solidification. This study is to use this model to analyze the role of f... A volume average solidification model is extended to incorporate fragmentation as the source of equiaxed crystals during mixed columnar-equiaxed solidification. This study is to use this model to analyze the role of fragmentation in the formation of as-cast structure. Test simulations are made for the solidification of a model alloy(Sn-10wt.%Pb) with two different geometries. The first one is a 2D rectangular domain(50 × 60 mm^2) as cooled from the top boundary. Solidification starts unidirectionally as columnar structure from the top. The solute(Pb) enriched interdendritic melt is heavier than the bulk melt, and sinks downwards, hence leads to solutal convection. Fragmentation phenomenon occurs near the columnar tip front. The fragments are transported out of the columnar region, and they continue to grow and sink, and finally settle down and pile up at the bottom. The growing columnar structure from the top and pile-up of equiaxed crystals from the bottom finally lead to a mixed columnar-equiaxed structure, in turn leading to a columnar-to-equiaxed transition(CET). The second geometry is a 3D plate, 100 × 60 ×10 mm^3, as cooled laterally from one side. It was cast experimentally and analyzed for the as-cast structure. The equiaxed fragments are produced in the solidification front and transported into the bulk melt, leading to a special pattern of as-cast structure: columnar structure in the cool wall side and equiaxed structure in the upper left corner near the hot wall side, extending downwards to the middle bottom region. Numerically calculated as-cast structures agree with the experiment results. 展开更多
关键词 MACROSTRUCTURE interdendritic fluid flow FRAGMENTATION
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