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乙醇溶剂中2-巯基苯并噻唑吸附于铁表面的SERS光谱研究 被引量:1
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作者 王欣 施建成 +4 位作者 杨海峰 a.harrison 曹佩根 王桂华 章宗穰 《光散射学报》 2003年第2期86-91,共6页
利用共焦显微拉曼系统研究了乙醇溶剂中2 巯基苯并噻唑(HMBT)在不同pH条件下吸附在ORC法粗糙化处理所得铁表面的SERS光谱。结果表明2 巯基苯并噻唑分子在酸性和中性溶液中通过环外S或环内N原子吸附于铁表面,而在碱性溶液中分子失去氢原... 利用共焦显微拉曼系统研究了乙醇溶剂中2 巯基苯并噻唑(HMBT)在不同pH条件下吸附在ORC法粗糙化处理所得铁表面的SERS光谱。结果表明2 巯基苯并噻唑分子在酸性和中性溶液中通过环外S或环内N原子吸附于铁表面,而在碱性溶液中分子失去氢原子,并通过静电相互作用吸附于铁表面上。 展开更多
关键词 乙醇溶剂 2-巯基苯并噻唑 表面吸附 SERS 表面增强拉曼光谱
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Numerical simulation of the natural fragmentation of explosively loaded thick walled cylinders 被引量:4
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作者 I.G.CULLIS P.DUNSMORE +2 位作者 a.harrison I.LEWTAS R.TOWNSLEY 《Defence Technology(防务技术)》 SCIE EI CAS 2014年第2期198-210,共13页
The ability to predict the natural fragmentation of an explosively loaded metal casing would represent a significant achievement.Physicallybased material models permit the use of small scale laboratory tests to charac... The ability to predict the natural fragmentation of an explosively loaded metal casing would represent a significant achievement.Physicallybased material models permit the use of small scale laboratory tests to characterise and validate their parameters.The model can then be directly employed to understand and design the system of interest and identify the experiments required for validation of the predictions across a wide area of the performance space.This is fundamentally different to the use of phenomenologically based material algorithms which require a much wider range of characterisation and validation tests to be able to predict a reduced area of the performance space.Eulerians numerical simulation methods are used to describe the fragmentation of thick walled EN24 steel cylinders filled with PBXN-109 explosive.The methodology to characterise the constitutive response of the material using the physically based Armstrong-Zerilli constitutive model and the Goldthorpe path dependent fracture model is described,and the results are presented.The ability of an Eulerian hydrocode to describe the fragmentation process and reproduce the experimentally observed fragment mass and velocity distributions is presented and discussed.Finally the suitability of the current experimental analysis methodology for simulation validation is addressed. 展开更多
关键词 数值模拟方法 爆炸加载 自然 厚壁 材料模型 破碎 验证实验 实验室试验
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