1 Results Polymerization of butadiene,isoprene and styrene and binary copolymerization of styrene with butadiene and isoprene were investigated using the catalyst Ti(η5-C5H5)(η2-MBMP)Cl (1) (MBMP=2,2′-methylenebis(...1 Results Polymerization of butadiene,isoprene and styrene and binary copolymerization of styrene with butadiene and isoprene were investigated using the catalyst Ti(η5-C5H5)(η2-MBMP)Cl (1) (MBMP=2,2′-methylenebis(6-tert-butyl-4-methylphenoxo) activated with methylaluminoxane (MAO).Syndiotactic polystyrene, cis-1,4- polybutadiene and cis-1,4-polyisoprene were obtained in good yields at 50 °C.Binary copolymerization of styrene with butadiene yielded block copolymers containing segments of cis-1,4-polybut...展开更多
文摘1 Results Polymerization of butadiene,isoprene and styrene and binary copolymerization of styrene with butadiene and isoprene were investigated using the catalyst Ti(η5-C5H5)(η2-MBMP)Cl (1) (MBMP=2,2′-methylenebis(6-tert-butyl-4-methylphenoxo) activated with methylaluminoxane (MAO).Syndiotactic polystyrene, cis-1,4- polybutadiene and cis-1,4-polyisoprene were obtained in good yields at 50 °C.Binary copolymerization of styrene with butadiene yielded block copolymers containing segments of cis-1,4-polybut...
