La1-xSrxMnO3-δ was synthesized by the Pechini＇s method. The XRD pattern and TEM indicate the formation of the perovskite without the presence of secondary phases. It was found that La0.8Sr0.2MnO3-δsample prepared a...La1-xSrxMnO3-δ was synthesized by the Pechini＇s method. The XRD pattern and TEM indicate the formation of the perovskite without the presence of secondary phases. It was found that La0.8Sr0.2MnO3-δsample prepared at 1000℃ in air atmospheres, contains about 13.11% of the manganese as Mn4＋ and 86.89% of the manganese as Mn3＋. The electric measurements were carded out for La0.8Sr0.2MnO3-δ nanoceramics by using impedance spectroscopy methods and found to be 0.1 S/cm at 250 ℃ similar to the typical value of La0.8Sr0.2MnO3-δ materials. Its dependence on reciprocal temperature shows quite complicated mechanism of conduction.展开更多
基金supported by Bilateral S & T Cooperation between the Hellenic Republic and the Republic of Poland (2005-2007)
文摘La1-xSrxMnO3-δ was synthesized by the Pechini＇s method. The XRD pattern and TEM indicate the formation of the perovskite without the presence of secondary phases. It was found that La0.8Sr0.2MnO3-δsample prepared at 1000℃ in air atmospheres, contains about 13.11% of the manganese as Mn4＋ and 86.89% of the manganese as Mn3＋. The electric measurements were carded out for La0.8Sr0.2MnO3-δ nanoceramics by using impedance spectroscopy methods and found to be 0.1 S/cm at 250 ℃ similar to the typical value of La0.8Sr0.2MnO3-δ materials. Its dependence on reciprocal temperature shows quite complicated mechanism of conduction.
