The electric measurements were carried out for La0.8Sr0.2CoO3 nanoceramics by using impedance spectroscopy methods. The resistance of sample was practically independent of frequency in measurement range. Its dependenc...The electric measurements were carried out for La0.8Sr0.2CoO3 nanoceramics by using impedance spectroscopy methods. The resistance of sample was practically independent of frequency in measurement range. Its dependence on reciprocal temperature showed quite complicated mechanism of conduction. The most striking property of investigated sample was its resistance decreasing with increasing applied polarization.展开更多
La1-xSrxMnO3-δ was synthesized by the Pechini's method. The XRD pattern and TEM indicate the formation of the perovskite without the presence of secondary phases. It was found that La0.8Sr0.2MnO3-δsample prepared a...La1-xSrxMnO3-δ was synthesized by the Pechini's method. The XRD pattern and TEM indicate the formation of the perovskite without the presence of secondary phases. It was found that La0.8Sr0.2MnO3-δsample prepared at 1000℃ in air atmospheres, contains about 13.11% of the manganese as Mn4+ and 86.89% of the manganese as Mn3+. The electric measurements were carded out for La0.8Sr0.2MnO3-δ nanoceramics by using impedance spectroscopy methods and found to be 0.1 S/cm at 250 ℃ similar to the typical value of La0.8Sr0.2MnO3-δ materials. Its dependence on reciprocal temperature shows quite complicated mechanism of conduction.展开更多
文摘The electric measurements were carried out for La0.8Sr0.2CoO3 nanoceramics by using impedance spectroscopy methods. The resistance of sample was practically independent of frequency in measurement range. Its dependence on reciprocal temperature showed quite complicated mechanism of conduction. The most striking property of investigated sample was its resistance decreasing with increasing applied polarization.
基金supported by Bilateral S & T Cooperation between the Hellenic Republic and the Republic of Poland (2005-2007)
文摘La1-xSrxMnO3-δ was synthesized by the Pechini's method. The XRD pattern and TEM indicate the formation of the perovskite without the presence of secondary phases. It was found that La0.8Sr0.2MnO3-δsample prepared at 1000℃ in air atmospheres, contains about 13.11% of the manganese as Mn4+ and 86.89% of the manganese as Mn3+. The electric measurements were carded out for La0.8Sr0.2MnO3-δ nanoceramics by using impedance spectroscopy methods and found to be 0.1 S/cm at 250 ℃ similar to the typical value of La0.8Sr0.2MnO3-δ materials. Its dependence on reciprocal temperature shows quite complicated mechanism of conduction.