To improve the surface properties of AZ91 magnesium alloy, Ni-SiC nanocomposite coatings with various SiC contents were pulse electrodeposited in modified Watts baths containing SiC nano-particles with the concentrati...To improve the surface properties of AZ91 magnesium alloy, Ni-SiC nanocomposite coatings with various SiC contents were pulse electrodeposited in modified Watts baths containing SiC nano-particles with the concentration of 0-15 g/L. The morphology of the coatings was studied by scanning electron microscope （SEM）. The SiC content of the coatings was measured by energy dispersive spectroscopy （EDS） analyzer. Microhardness measurement of the coatings showed up to 600% enhancement for the sample produced from the bath with 15 g/L SiC. The corrosion behavior of the coated AZ91 alloy was investigated by potentiodynamic polarization method. The results reveal a significant improvement in the corrosion resistance, that is, the corrosion current density decreases from 0.13 mA/cm2 for uncoated specimen to 1.74x10-6 mA/cm2 for the sample coated from the bath containing 15 g/L SiC and the corrosion potential increases from -1.6 V for uncoated specimen to -0.31 V for the sample coated from the bath. The wear resistance of both coated and uncoated samples was evaluated by pin-on-disc tribotester. The results show that the wear volume loss of coated sample is 8 times less than the bare alloy.展开更多
Defect-free butt joints of 3003 Al alloy to mild steel plates with 3 mm thickness were performed using friction stir welding （FSW）. A heat input model reported for similar FSW was simplified and used to investigate ...Defect-free butt joints of 3003 Al alloy to mild steel plates with 3 mm thickness were performed using friction stir welding （FSW）. A heat input model reported for similar FSW was simplified and used to investigate the effects of welding speed, rotation speed and tool shoulder diameter on the microstructure and properties of dissimilar welds. The comparison between microstructure, intermetallics and strength of welds shows the good conformity between the results and the calculated heat input factor （HIF） achieved from the model. The joint strength is controlled by Al/Fe interface at HIF of 0.2-0.4, by TMAZ at HIF of 0.4-0.8 and by intermetallics and/or defects at HIF0.8.展开更多
Ni–Co coatings with various cobalt contents were electrodeposited from modified Watts bath. The effect of cobalt content on electrodeposition mechanism of the coatings was studied by electro-chemical impedance spectr...Ni–Co coatings with various cobalt contents were electrodeposited from modified Watts bath. The effect of cobalt content on electrodeposition mechanism of the coatings was studied by electro-chemical impedance spectroscopy method （EIS）. Surface morphology and crystallographic structure of the coatings were investigated by means of SEM and XRD. Mechanical properties of the coatings were determined using Vickers microhardness and tensile tests. It was found that with increasing the Co2＋ions in electroplating bath, the charge transfer resistance （Rct）of Ni-Co film increased whereas the Warburg impedence decreased. This may be due to enhancement in coverage of cathode surface by Co（OH）2 and higher diffusion rate of metal ions towards cathode surface, respectively. Also, with increasing the cobalt content in the bath, cobalt content in the alloy coating increased anomalously and （111） texture consolidated gradually. With increasing the cobalt content up to 45% in alloy coating, the grain size decreased and consequently, hardness and strength of the alloy increased. Further enhancement of cobalt content up to 55% led to a little decrease in hardness and strength. The maximum ductility was observed for Ni-25%Co coating due to relatively small grain size and compact structure.展开更多
文摘To improve the surface properties of AZ91 magnesium alloy, Ni-SiC nanocomposite coatings with various SiC contents were pulse electrodeposited in modified Watts baths containing SiC nano-particles with the concentration of 0-15 g/L. The morphology of the coatings was studied by scanning electron microscope （SEM）. The SiC content of the coatings was measured by energy dispersive spectroscopy （EDS） analyzer. Microhardness measurement of the coatings showed up to 600% enhancement for the sample produced from the bath with 15 g/L SiC. The corrosion behavior of the coated AZ91 alloy was investigated by potentiodynamic polarization method. The results reveal a significant improvement in the corrosion resistance, that is, the corrosion current density decreases from 0.13 mA/cm2 for uncoated specimen to 1.74x10-6 mA/cm2 for the sample coated from the bath containing 15 g/L SiC and the corrosion potential increases from -1.6 V for uncoated specimen to -0.31 V for the sample coated from the bath. The wear resistance of both coated and uncoated samples was evaluated by pin-on-disc tribotester. The results show that the wear volume loss of coated sample is 8 times less than the bare alloy.
文摘Defect-free butt joints of 3003 Al alloy to mild steel plates with 3 mm thickness were performed using friction stir welding （FSW）. A heat input model reported for similar FSW was simplified and used to investigate the effects of welding speed, rotation speed and tool shoulder diameter on the microstructure and properties of dissimilar welds. The comparison between microstructure, intermetallics and strength of welds shows the good conformity between the results and the calculated heat input factor （HIF） achieved from the model. The joint strength is controlled by Al/Fe interface at HIF of 0.2-0.4, by TMAZ at HIF of 0.4-0.8 and by intermetallics and/or defects at HIF0.8.
文摘Ni–Co coatings with various cobalt contents were electrodeposited from modified Watts bath. The effect of cobalt content on electrodeposition mechanism of the coatings was studied by electro-chemical impedance spectroscopy method （EIS）. Surface morphology and crystallographic structure of the coatings were investigated by means of SEM and XRD. Mechanical properties of the coatings were determined using Vickers microhardness and tensile tests. It was found that with increasing the Co2＋ions in electroplating bath, the charge transfer resistance （Rct）of Ni-Co film increased whereas the Warburg impedence decreased. This may be due to enhancement in coverage of cathode surface by Co（OH）2 and higher diffusion rate of metal ions towards cathode surface, respectively. Also, with increasing the cobalt content in the bath, cobalt content in the alloy coating increased anomalously and （111） texture consolidated gradually. With increasing the cobalt content up to 45% in alloy coating, the grain size decreased and consequently, hardness and strength of the alloy increased. Further enhancement of cobalt content up to 55% led to a little decrease in hardness and strength. The maximum ductility was observed for Ni-25%Co coating due to relatively small grain size and compact structure.
