With the new theoretical approach i.e. lie algebraic approach, we have calculated the infrared spectra of Phosphine in the range from 3000 cm-1 to 9500 cm-1 and Nitrogen Trifluoride in the range from 900 cm-1 to 4500 ...With the new theoretical approach i.e. lie algebraic approach, we have calculated the infrared spectra of Phosphine in the range from 3000 cm-1 to 9500 cm-1 and Nitrogen Trifluoride in the range from 900 cm-1 to 4500 cm-1. The model Hamiltonian, so constructed, seems to describe the P-H and N-F stretching modes accurately with only four numbers of parameters.展开更多
文摘With the new theoretical approach i.e. lie algebraic approach, we have calculated the infrared spectra of Phosphine in the range from 3000 cm-1 to 9500 cm-1 and Nitrogen Trifluoride in the range from 900 cm-1 to 4500 cm-1. The model Hamiltonian, so constructed, seems to describe the P-H and N-F stretching modes accurately with only four numbers of parameters.
