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Zoned Zircon from Eclogite Lenses in Marbles from the Dabie-Sulu UHP Terrane,China: A Clear Record of Ultra-deep Subduction and Fast Exhumation 被引量:19
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作者 LIU Fulai a. gerdes +2 位作者 P. T. ROBINSON XUE Huaimin YE Jianguo 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2007年第2期204-225,共22页
Eclogite lenses in marbles from the Dabie-Sulu ultrahigh-pressure (UHP) terrane are deeply subducted meta-sedimentary rocks. Zircons in these rocks have been used to constrain the ages of prograde and UHP metamorphi... Eclogite lenses in marbles from the Dabie-Sulu ultrahigh-pressure (UHP) terrane are deeply subducted meta-sedimentary rocks. Zircons in these rocks have been used to constrain the ages of prograde and UHP metamorphism during subduction, and later retrograde metamorphism during exhumation. Inherited (detrital) and metamorphic zircons were distinguished on the basis of transmitted light microscopy, cathodoluminescence (CL) imaging, trace element contents and mineral inclusions. The distribution of mineral inclusions combined with CL imaging of the metamorphic zircon make it possible to relate zircon zones (domains) to different metamorphic stages. Domain 1 consists of rounded, oblong and spindly cores with dark-luminescent images, and contains quartz eclogite facies mineral inclusion assemblages, indicating formation under high-pressure (HP) metamorphic conditions of T = 571-668℃ and P =1.7-2.02 GPa. Domain 2 always surrounds domain 1 or occurs as rounded and spindly cores with white-luminescent images. It contains coesite eclogite facies mineral inclusion assemblages, indicating formation under UHP metamorphic conditions of T = 782-849℃ and P 〉 5.5 GPa. Domain 3, with gray-luminescent images, always surrounds domain 2 and occurs as the outermost zircon rim. It is characterized by low-pressure mineral inclusion assemblages, which are related to regional amphibolite facies retrograde metamorphism of T = 600- 710℃ and P = 0.7-1.2 GPa. The three metamorphic zircon domains have distinct ages; sample H1 from the Dabie terrane yielded SHRIMP ages of 245 ± 4 Ma for domain 1, 235 ± 3 Ma for domain 2 and 215± 6 Ma for domain 3, whereas sample H2 from the Sulu terrane yielded similar ages of 244 ± 4 Ma, 233 ± 4 Ma and 214 ± 5 Ma for Domains 1, 2 and 3, respectively. The mean ages of these zones suggest that subduction to UHP depths took place over 10-11 Ma and exhumation of the rocks occurred over a period of 19-20 Ma. Thus, subduction from - 55 km to 〉 160 km deep mantle depth took place at rates of approximately 9.5-10.5 km/Ma and exhumation from depths 〉160 km to the base of the crust at -30 km occurred at approximately 6.5 km/Ma. We propose a model for these rocks involving deep subduction of continental margin lithosphere followed by ultrafast exhumation driven by buoyancy forces after break-off of the UHP slab deep within the mantle. 展开更多
关键词 zoned zircon SHRIMP U-Pb dating ultra-deep subduction fast exhumation eclogite lenses in marble Dabie-Sulu UHP belt
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复碱化混凝土孔溶液的pH值(英文) 被引量:6
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作者 a. gerdes F. H. Wittmann 《建筑材料学报》 EI CAS CSCD 2003年第2期111-117,共7页
碳化混凝土的复碱化是用碳酸钙缓冲溶液浸渍混凝土的电化学过程,目的是使混凝土孔溶液的pH值稳定在10以上,从而防止混凝土的进一步碳化.然而,该方法的实际应用表明:虽然孔溶液中已明显含有足量的碱(Na+,K+,Li+),但pH值仍降到10以下.本... 碳化混凝土的复碱化是用碳酸钙缓冲溶液浸渍混凝土的电化学过程,目的是使混凝土孔溶液的pH值稳定在10以上,从而防止混凝土的进一步碳化.然而,该方法的实际应用表明:虽然孔溶液中已明显含有足量的碱(Na+,K+,Li+),但pH值仍降到10以下.本文通过试验提出了一个用以解释pH值随时间降低的假说,结果表明:由于混凝土孔溶液中存在溶解的硫酸盐,因此单纯提高孔溶液的碱离子(碳酸盐)相对含量,不能确保其pH值高于10.用提出的化学机理可解释混凝土电化学复碱化技术实际应用中观察到的现象,但是,由于混凝土孔溶液中溶解离子相互作用十分复杂,目前还不能在复碱化技术中对其加以考虑,因此复碱化技术尚不能被进一步推荐应用. 展开更多
关键词 碳化混凝土 复碱化 硫酸盐 孔溶液 PH值
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