The selective oxidation of toluene and its derivatives is extremely important in the chemical industry.The use of photocatalysis in organic synthesis has attracted considerable attention among synthetic chemists becau...The selective oxidation of toluene and its derivatives is extremely important in the chemical industry.The use of photocatalysis in organic synthesis has attracted considerable attention among synthetic chemists because of its ＂green＂ environmental characteristics.In this study,nanoscale Bi_2WO_6with a flower-like morphology was found to be a highly efficient photocatalyst in the catalytic oxidation of toluene and its derivatives using O_2 as the oxidant.The loading of Pd nanoparticles as a cocatalyst onto the flower-like Bi_2WO_6 was found to produce a significant enhancement in the catalytic activity.Mechanistic investigation showed that the superior performance of Pd/Bi_2WO_6 could be attributed to the improvement of both the reductive and oxidative abilities of Bi_2WO_6 by the loading of the cocatalyst.展开更多
文摘采用数值模拟的方法研究浇注式沥青混凝土摊铺时钢桥面摊铺温度场及温度变形效应.建立钢箱梁温度场模型,对浇注式沥青混凝土摊铺过程中钢桥面温度场分布规律进行了数值模拟,拟合出最不利温度荷载公式.根据时空等效原理建立考虑施工过程的温度荷载公式,计算钢桥面板的局部温度变形,并分析其对铺装效果的影响.研究结果表明,摊铺10 min后钢板局部迅速升温至120℃,并在17 min后达到最大温度123℃,此阶段摊铺温度对钢板结构的影响较大;摊铺区域钢板会产生局部温度变形,最大竖向变形达到7.5 mm,使摊铺层局部厚度有偏差,模拟值接近1 mm.
基金supported by the National Natural Science Foundation of China(21322202,21472187)the National Basic Research Program of China(2010CB833300)~~
文摘The selective oxidation of toluene and its derivatives is extremely important in the chemical industry.The use of photocatalysis in organic synthesis has attracted considerable attention among synthetic chemists because of its ＂green＂ environmental characteristics.In this study,nanoscale Bi_2WO_6with a flower-like morphology was found to be a highly efficient photocatalyst in the catalytic oxidation of toluene and its derivatives using O_2 as the oxidant.The loading of Pd nanoparticles as a cocatalyst onto the flower-like Bi_2WO_6 was found to produce a significant enhancement in the catalytic activity.Mechanistic investigation showed that the superior performance of Pd/Bi_2WO_6 could be attributed to the improvement of both the reductive and oxidative abilities of Bi_2WO_6 by the loading of the cocatalyst.
