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Tuning multifunctional stimuli-responsive behaviour through halogen exchange in hybrid ionic[(CH_(3)CH_(2))_(3)N(CH_(2)X)]_(2)[MnCl_(4)](X=Cl,Br)

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摘要 Hybrid metal halide materials have attracted significant attention due to their diverse functional properties.In this study,we prepared,characterized,and evaluated the multifunctional properties of two hybrid tetrachloromanganate(II)compounds with the general formula[(CH_(3)CH_(2))_(3)N(CH_(2)X)]_(2)[MnCl_(4)],where X is Cl or Br.
出处 《Inorganic Chemistry Frontiers》 2025年第22期7282-7293,共12页 无机化学前沿(英文)
基金 financial support from grant PID2021-122532OB-I00 funded by MCIN/AEI/10.13039/501100011033 ERDF A way of making Europe,the project PDC2021-121076-I00 funded by MCIN/AEI/10.13039/501100011033 by the European Union Next GenerationEU/PRTR the projects ED431C 2022/39 and ED431F 2023/33 funded by Xunta de Galicia This publication is part of the grant RYC2021-033040-I funded by MCIN/AEI/10.13039/501100011033 from European Union“NextGenerationEU”/PRTR”,and granted to J.M.B.-G This researcher is also grateful for the support received by UDC-Inditex InTalent Programme.J.G.-B.and M.G.acknowledge Xunta de Galicia for Postdoctoral(ED481B-2024) Predoctoral(ED481A-2023)Fellowships,respectively P.D.-R.thanks Ministerio de Ciencia,Innovación y Universidades for a FPU Fellowship(FPU23/00091) A.G.-F.and U.B.C.thank the Swedish Research Council(Grant No.VR 2022-03168) the Göran Gustafsson foundation for funding.This work was partially supported by the Wallenberg Initiative Materials Science for Sustainability(WISE)funded by the Knut and Alice Wallenberg Foundation.A.G.-F acknowledges support from a Beatriz Galindo junior fellowship(BG23/00033)from the Spanish Ministry of Science and Innovation.The authors thank ESRF for the award of beam time(A01-2-1291 on BM01) Open access publication fees were covered by Universidade da Coruña/CISUG.

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