摘要
It is highly desirable to mimic the ratchet-like multi-electron transfer of the electron transport chain(ETC)by artificial systems and impose dual-mode anaerobic denitrification and aerobic oxidation on organic compounds to produce value-added fine chemicals.However,the extreme complexity of biological structures hampers their direct mimicry.In this article,we report a new continuous and directional photoinduced-electron transfer(PET)method to mimic the ETC process of natural enzymes using metal–organic frameworks(MOFs)as the platform.
基金
funded by the National Natural Science Foundation of China(No.22472020,22301028,21971031,21820102001,21231003)
Liaoning Province Science and Technology Plan Joint Project(No.2023JH2/101700297)
Foreign Youth Talent Program(No.QN2023127001L)
Fundamental Research Funds for the Central Universities(No.DUT24YG123)
Our special thanks to Dr Rui Cai,Dr Dan Wang,and Dr Liyan Zhang at the Instrumental Analysis Center and State Key Laboratory of Fine Chemicals,Dalian University of Technology,for their assistance with experiments and analyses on the fluorescence,EPR,and ground-state UV/vis/IR absorption studies,respectively.
