摘要
In this piece of work,CuI and its catalysis of the aerobic oxidation of alcohols have been mechanistically investigated with N,N,N’,N’-tetramethylethylenediamine(TMEDA)as a ligand and 2,2,6,6-tetramethylpiperidine-N-oxyl(TEMPO)as a co-catalyst.The system demonstrates excellent catalytic activity for selective aerobic oxidation of a wide range of primary alcohols under ambient conditions both in quantitative yield and on a preparative scale.
基金
National Natural Science Foundation of China(grant no.21571083)
the Natural Science Foundation of Zhejiang Province(grant no.LY18B010007 and LY19B010001)
the Government of Zhejiang Province(Qianjiang Professorship for XL)and Jiaxing University(Summit Program of Jiaxing University for Leading Talents)for supporting this work.
