[M(OH)_(2)]_(3)(IO_(3))(SeO_(4))·H_(2)O(M=Ga and In):metal iodate-selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

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摘要 Exploration of new iodates is crucial due to their splendid applications in the nonlinear optical(NLO)field.Two new IIIA metal iodate-selenates,namely,[M(OH)_(2)]_(3)(IO_(3))(SeO_(4))·H_(2)O(M=Ga and In),have been successfully synthesized using the hexagonal tungsten oxide(HTO)framework as an ideal structural template.Isostructural[M(OH)_(2)]_(3)(IO_(3))(SeO_(4))·H_(2)O(M=Ga and In)crystallize in the polar space group P6_(3)mc.

作者 Qian-Qian Chen Chun-Li Hu Bing-Xuan Li Jiang-Gao Mao

机构地区 State Key Laboratory of Structural Chemistry

出处《Inorganic Chemistry Frontiers》 2023年第10期3121-3130,共10页 无机化学前沿(英文)

基金 supported by the National Natural Science Foundation of China(no.22031009,21921001,and 21975256).

关键词 iodate selenates new materials exploration nonlinear optical materials hexagonal tungsten oxide topology

分类号 TB34 [一般工业技术]

Inorganic Chemistry Frontiers

2023年第10期

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[M(OH)_(2)]_(3)(IO_(3))(SeO_(4))·H_(2)O(M=Ga and In):metal iodate-selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

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