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Tailoring the d-band center of porous CoS_(2)nanospheres via low-electronegative Fe for weakened OH^(*)adsorption and boosted oxygen evolution

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摘要 The development of high-performance metallic cobalt pyrite OER catalysts with suitable electronic structures remains a challenge.In this paper,a low-electronegative Fe-substituted cobalt pyrite(Fe_(x)Co_(1-x))S_(2)OER catalyst with controllable morphology and electronic structure was designed and prepared,and it exhibited excellent catalytic activity owing to the conversion of(Fe_(x)Co_(1-x))S_(2)to Fe-CoOOH during the OER process.
出处 《Inorganic Chemistry Frontiers》 2023年第19期5668-5677,共10页 无机化学前沿(英文)
基金 support from the National Natural Science Foundation of China(Grant no.21875039) the Project on the Integration of Industry-Education-Research of Fujian Province(2021H6020).

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