摘要
A new organic–inorganic ABX_(3)perovskite-type semiconducting hybrid,N-methylpyrrolidinium trichlorocadmate(MPCC),has been synthesized.It is found that MPCC exhibits semiconducting behaviour with an optical bandgap of∼4.65 eV,as well as remarkable dielectric switching properties.It displays a structural phase transition(SPT)at T_(c)=254 K,being confirmed by DSC and specific heat measurements.
基金
supported by the NSFC(21525104,21622108,21601188,91422301,21373220,51402296,21571178,51502288 and 51502290)
the NSF for Distinguished Young Scholars of Fujian Province(2016J06012)
the NSF of Fujian Province(2015J05040)
the Strategic Priority Research Program of the CAS(XDB20000000)
the Youth Innovation Promotion of CAS(2014262,2015240 and 2016274)
the support from the“Chunmiao Projects”of Haixi Institute of CAS(CMZX-2014-003)
Z.S.acknowledges the support from State Key Laboratory of Luminescence and Applications(SKLA-2016-09).
