摘要
Two nucleobase-incorporated metal-organic materials were designed,synthesized and structurally characterized.PCN-530 is among the few examples of metal-organic frameworks that utilize adenine as a constructional unit,while TMOP-1 is the first existing example of a crystallographically characterized nucleobase-incorporated metal-organic polyhedron.This work also offers a general perspective for the design and synthesis of nucleobase-incorporated metal-organic materials.
基金
supported as part of the Center for Gas Separations Relevant to Clean Energy Technologies
an Energy Frontier Research Center funded by the U.S.Department of Energy(DOE),Office of Science,Office of Basic Energy Sciences under Award Number DE-SC0001015
The authors also acknowledge the DOE grant DE-FC36-07GO17033
the Welch Foundation A-1725.
