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(Ce,Tb)ZnAl_(11)O_(19)荧光粉合成方法的改进

IMPROVEMENT OF THE SYNTHETIC METHOD OF(Ce,Tb)ZnAl_(11)O_(19)PHOSPHOR
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摘要 本文报导了SiO_2存在下,Tb^(3+)离子激活的稀土多铝酸盐的合成方法。研究了荧光粉组成和助熔剂对荧光粉合成条件和性能的影响。结果表明,制备荧光粉时,当有SiO_2存在于合成原料中,灼烧温度将有较大幅度的降低。由文献报导的1550℃降至1300℃左右。 The procedure for synthesis of(Ce,Tb)ZnAl_(11)O_(19) Phosphor has been improv-ed.It was shown that the burning tempreture of synthesis was reduced deeply bythe addition of SiO_2.The optimum burning tempreture was shown to be about1320℃.Other parameters influencing luminescence of the phosphor were also stu-elied in this paper.The intueduction of M~Ⅰ M~Ⅱ or M~Ⅲ cations into the phosphor was shown tohave different influence on the luminescence of the phosphor.M~Ⅱ cations werebeneficial and M~Ⅰ cations were harmful.Other expesimental conditions,such as burning time of sample,were also opti-miged.
机构地区 晓庄学院化学系
出处 《晓庄学院自然科学学报》 CAS 1989年第1期43-47,共5页 Journal of Natural Science of Hunan Normal University
关键词 荧光粉 多铝酸盐 稀土 合成 synthesis phosphor luminescence
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