摘要
选用甲基葡萄糖苷和邻苯二甲酸酐为原料,在三乙胺的催化作用下合成了具有配位能力的齿状有机酯配体甲基葡萄糖苷芳香酸酯(MGAE)(C15H18O9,C15H16O8,C22H30O14,C23H22O12,C31H26O15或C39H30O18)配体;然后,将该新型有机酯配体与金属盐溶液在模板剂三乙胺的作用下经配位制备出一系列MGAE金属有机化合物,并采用FT-IR,XRD,TGA,FSEM,EDS和BET等表征手段对所得的MGAE金属有机化合物进行表征。结果表明:配位过程中主要是MGAE中的羰基参与反应,且影响配合物性能的主要是MGAE中的有机配体和金属阳离子。
Dentate organic ester ligandsmethyl glucoside aromatic ester based ligands （MGAE ligand） （C15H1809, C15H1608, C22H30O14, C23H22O12, C31H26015 or C39H30Ols） with complexation ability were, through the catalysis of triethylamine, synthesized using methyl glucoside and phthalie anhydride as selected raw materials. Then, a series of MGAE ligand based metal-organic coordination compounds were prepared in the involvement of triethylamine as a template agent through complexing the new type of organic ligands with metal salt solution, Then the MGAE ligand based complexes were characterized using FT-IR, XRD, TGA, FSEM, EDS and BET. The results showed that the complexation is chiefly due to the involvement of carbonyl in the MGAE ligand and the performance of complexes is mainly influenced by the MGAE ligands and metal cations.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2014年第5期1073-1078,共6页
Chinese Journal of Inorganic Chemistry
基金
四川省科技厅国际合作项目(No.2011HH0020)
西南科技大学博士基金(No.10zx7104)
西南科技大学平台科研基金(No.13zxpt08)
