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汽车尾气催化净化过程中的水煤气反应和蒸汽转换反应 被引量:5

Water-gas shift and steam reforming reactions in the catalytic after-treatment of automotive exhaust gas
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摘要 本研究主要考察了不同组成的汽车尾气净化催化剂在无氧条件下对 CO水煤气反应和 HC蒸汽转换反应的催化性能。结果表明 ,在催化剂中添加一定量的稀土金属氧化物( La2 O3、Ce O2 )和过渡金属氧化物 ( Ni O) ,均有利于改善催化剂对 CO水煤气反应和 HC蒸汽转换反应的催化性能。此外还考察了水蒸汽含量以及空速的变化对反应的影响。 The performance of different catalysts in the water-gas shift and steam reforming reactions under rich condition was studied experimentally.Experimental results showed that rare earth oxides(La 2O 3、CeO 2)and transition metal oxides(NiO)can improve significantly the activity of automotive catalyst for the water-gas shift and steam reforming reactions.Influence of water vapor content and space velocity on the two reactions was also investigated.
出处 《工业催化》 CAS 2000年第5期29-33,共5页 Industrial Catalysis
关键词 水煤气反应 蒸汽转换反应 汽车尾气净化 催化剂 water-gas shift reaction steam reforming reaction exhaust gas automotive catalyst
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参考文献5

  • 1Bunluesin T,Gorte R T,Graham G W.Studies of water gas-shift reaction on ceria surported Pt , Pd and Rh:implications for oxygen-storage properties[].Applied Catalysis B Environmental.1998
  • 2Shido T,Iwasawa Y.Regulation of Reaction Intermediate by Reactant in the Water -Gas Shift Reaction on CeO2 , in Relation to Reactant -Promoted Mechanism[].Journal of Catalysis.1992
  • 3Barbier J Jr,Duprez D.Steam effects in three-way catalysis[].Applied Catalysis B Environmental.1994
  • 4Shido T,Iwasawa Y.Reactant -Promoted Reaction Mechanism for Water -Gas Shift Reaction on RhDoped CeO2[].Journal of Catalysis.1993
  • 5Barbier J Jr,Duprez D.Reactivity of steam in exhaust gas catalysis: Ⅰ Steam and oxygen steam conversion of carbon monoxide and of propane over Pt Rh catalysts[].Applied Catalysis B Environmental.1993

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