摘要
以2-(2′-氰乙硫基)-3,6,7-三甲硫基四硫富瓦烯为原料,在四甲基氢氧化铵作用下,通过Mn2+离子催化偶联反应合成了1个二硫架桥的二聚四硫富瓦稀化合物1,化合物1的结构经红外光谱、扫描电子显微镜、元素分析、核磁共振氢谱、质谱进行了表征.循环伏安结果显示化合物具有2对明显的可逆氧化还原峰.为"桥式"四硫富瓦稀衍生物的合成提出了一种新方法.
With tetramethyl mmonium deprotection of 2-cyanoethylthio-3,6,7-tri（methylthio）tetrathiafulvalene and manganese-catalysed coupling reaction,a disulfide-bridged TTF dimer was synthesized.The structure of compound was characterized by IR spectra,SEM,elemental analysis,1HNMR spectrum,and GCT-TOF MS.Moreover,the compound displays two couples of cathodic and anodic peaks in the cyclic voltammogram,and the redox processes are reversible.This is a new method for preparing bridged tetrathiafulvalenes.
出处
《分子科学学报》
CAS
CSCD
北大核心
2013年第2期156-159,共4页
Journal of Molecular Science
基金
河北省科学技术研究与发展计划项目(11215178)
