摘要
用RHF/AM1方法研究了烷酰基膦烷衍生物的热分解反应机理.研究结果表明,反应所循的路径是经一个四元环过渡态,消去R1R2R3PO,生成炔烃的过程.
AM1 molecular orbital methods using the restricted Hartree Fock(RHF)calculations has been applied to investigate the pyrolysis of β oxoethylidenephosphorane.The results obtained indicate that the reaction pathway is a four member ring transition state process of elimination R 1R 2R 3P O to yield ethynes.
出处
《江西师范大学学报（自然科学版）》
CAS
1999年第3期248-251,共4页
Journal of Jiangxi Normal University(Natural Science Edition)
基金
江西省自然科学基金
