摘要
在０．２ｍｏｌ／ＬＨ２ＳＯ４－１０％乙醇介质中及紫外光照射条件下磷钼杂多酸光还原为磷钼蓝（λｍａｘ＝７８０ｎｍ）。据此建立了一个测定０．０５～２．０μｇ／ｍＬ磷的光化学分析新方法，并用于试样分析。探讨了光化学反应机理。
Under the conditions of 0 2mol/L sulphuric acid -10% ethanol medium and irradiation of UV-light, molybdophosphate heteropoly acid is reduced to its heteropoly blue (λ max =780nm) On those grounds,a new photochemical spectrophotometric method for 0 05～2 0μg/mL phosphorous has described, and applied to determining phosphorous in real samples The photochemical mechanism is also discussed
出处
《分析测试技术与仪器》
CAS
1998年第2期103-107,共5页
Analysis and Testing Technology and Instruments
关键词
磷
光化学
分析
磷钼杂多酸
磷钼蓝
phosphorous photochemistry of heteropoly acid photochemical analysis
