摘要
采用Ｘ射线粉末物相分析、红外及紫外漫反射光谱、差热分析、ＮＨ３脱附法和气体吸附等测试手段研究了ＴｉＳｉ沸石ＴＳ１，ＴＳ２，ＴｉＺＳＭ４８及钛酸钠、钛铝酸钠和钛酸铜分子筛的性能和结构．利用苯酚羟基化反应证明了含有ＴｉＯ４四配位结构单元的沸石分子筛具有催化氧化活性．考察了各种实验条件对苯酚羟基化反应的影响．
The structure and physicochemical properties of zeolites TS1, TS2, TiZSM48, sodium titanate, copper titanate and sodium titanoaluminate were studied by using the methods of XRD, IR, UVVIS, DTA, NH3TPD. It was proved that the zeolites in which having the structural unit of four coordination TiO4 show catalytic activity for the reaction of phenol hydroxylation. Influence of experimental conditions on the reaction of hydroxylation were also investigated in detail.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
1997年第6期488-492,共5页
基金
国家自然科学基金
关键词
钛酸盐
钛硅沸石
分子筛催化剂
苯酚
羟基化反应
Titanate, Titaniumsilicon zeolite, Molecular sieve catalyst, Phenol, Hydroxylation
