摘要
本文报道标题化合物（其中γＣＨ３ｐｙ是对甲基吡啶，ｍｎｔ＝ＣＮＣＮＳ－Ｓ－）的合成、鉴定和单晶结构。化合物晶体属三钭晶系，Ｐ１空间群，晶胞内分子数为２。分子中与Ｐｄ（Ⅱ）配位的四个原子呈平面四方形。讨论了结构与二阶、三阶非线性光学效应的关系。
This paper describes the synthesis, characterization and X ray single crystal structure of the new title compound where γ CH 3py is γ methylpyridine and mnt represents maleonitriledithiolate. It crystallizes in triclinic system and space group P 1 . It is confirmed that four coordinating atoms arround Pd(Ⅱ) cation form a square planar configuration. The relation between structure and the second and third order nonlinear optical properties is preliminarily discussed.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1997年第2期173-178,共6页
Chinese Journal of Inorganic Chemistry
基金
国家科委攀登计划
国家教委资助
关键词
晶体结构
钯配合的
平面四方型
非线性光学效应
synthesis\ \ \ crystal structure\ \ \ palladium\ \ \ square planar nonlinear optical property
