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直接甲醇燃料电池阳极催化剂的研究进展 被引量：19

Research progress of anode catalysts for direct methanol fuel cell
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摘要 直接甲醇燃料电池(DMFC)阳极催化剂是DMFC的关键材料之一,其电化学活性的大小对燃料电池的性能及成本起着关键作用。简要介绍了DMFC阳极催化剂的电催化氧化机理,并探讨了在目前研究中存在的问题和今后努力的方向,对研究DMFC阳极催化剂具有很好的参考价值。 The anode catalyst of direct methanol fuel cell （DMFC） is one of the key materials for DMFC, The electrochemical activity of the catalysts affects the performance and cost of the fuel cell. The electro oxidation mechanism of DMFC anode catalyst was introduced; exiting questions and developing direction were discussed, which had excellent referenced value for studying anode catalysts of DMFC.
作者 李金峰 宋焕巧 邱新平
机构地区 清华大学化学系有机光电子与分子工程教育部重点实验室 北京科技大学材料科学与工程学院
出处 《电源技术》 CAS CSCD 北大核心 2007年第2期167-170,共4页 Chinese Journal of Power Sources
基金 国家"973"基金资助项目(2002CB211803)
关键词 直接甲醇燃料电池 阳极催化剂 电催化氧化机理 direct methanol fuel cells （DMFC） anode catalyst electro oxidation mechanism
分类号 TM911.4 [电气工程—电力电子与电力传动]
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参考文献13

  • 1周卫江,周振华,李文震,孙公权,辛勤.直接甲醇燃料电池阳极催化剂研究进展[J].化学通报,2003,66(4):228-234. 被引量：28
  • 2DUBAU L,HAHN F,COUTANCEAU C,et al.On the structure effects of bimetallic PtRu electrocatalysts towards methanol oxidation[J].J Electroanal Chem,2003,(8):407-415.
  • 3DESAI S,NEUROCK M.A first principles analysis of CO oxidation over Pt and Pt66.7%Ru33.3%(111) surfaces[J].Electrochim Acta,2003,(48):3 759-3 773.
  • 4CHEN W X,ZHAO J,LEE J Y,et al.Microwave heated polyol synthesis of carbon nanotubes supported Pt nanoparticles for methanol electrooxidation[J].Mater Chem Phys,2005,(91):124-129.
  • 5黄红良,隋静,陈红雨,李伟善.国内外直接甲醇燃料电池研究进展[J].电池工业,2004,9(6):320-324. 被引量：8
  • 6CHOI J H,PARK K W,LEE H K,et al.Nano-composite of PtRu alloy electrocatalyst and electronically conducting polymer for use as the anode in a direct methanol fuel cell[J].Electrochim Acta,2003,(48):2 781-2 789.
  • 7KUA J,GODDARD W A.Oxidation of methanol on 2nd and 3rd row group Ⅶ transition metals (Pt,Ir,Pd,Rh and Ru):application to direct methanol fuel cells[J].J Am Chem Soc,1999,121(47):10 928-10 941.
  • 8KAWAGUCHI T,SUGIMOTO W,MURAKAMI Y,et al.Temperature dependence of the oxidation of carbon monoxide on carbon supported Pt,Ru,and PtRu[J].Electrochem Commun,2004,(6):480-483.
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  • 10DINH H N,REN X M,GARZON F H,et al.Electrocatalysis in direct methanol fuel cells:in-situ probing of PtRu anode catalyst surfaces[J].J Electroanal Chem,2000,(419):222-233.

二级参考文献34

  • 1苏爱华,李长志,孙公权,张颖,陆天虹.Pt／C－SPE和PtRu／C－SPE膜电极上甲醇的催化氧化[J].电化学,1995,1(4):397-401. 被引量：12
  • 2Gotz M, Wendt H. Composite electrocatalysts for anodic methanol and methanol- reformat oxidation[J] . J Applied Electrochemistry, 2001, 31: 811 - 817.
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  • 7Hong W H, Kim Y J, Choi W C, et al. Reducing methanol cross- over with Pd- plugged proton conductive membrane for a direct methanol fuel cells[A]. 2002 Fuel Cell Seminar [C]. California,2002. 223 - 226.
  • 8Si Y C, Lin J C, Kunz H R, et al. Nafion(r) -zirconium hydrogen phosphate composite membranes for high temperature direct methanol fuel cells(DMFC) [A] . 2002 Fuel Cell Seminar[C]. California, 2002. 185 - 188.
  • 9Zelenay P, Brosha E, Davey J, et al. Direct methanol fuel cells. Hydrogen, Fuel Cells and Infrastructure Technologies [A]. 2002 Fuel Cell Seminar[C]. California, 2002. 441 -446.
  • 10Stolten D, Mergel J, Dohle H, et al. Development of direct methanol fuel cell stacks[A]. 2002 Fuel Cell Seminar[C].California, 2002. 1 004 - 1 007.

共引文献32

同被引文献185

引证文献19

二级引证文献43

电源技术
2007年 第2期

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