摘要
分别研究了温度对壬基酚聚氧乙烯醚(NP-10)/水体系和十二烷基聚氧乙烯醚(AEO12)/水体系形成的立方相液晶线性黏弹性的影响。5~23.5℃,NP-10/水体系形成的双连续立方相表现出明显的黏弹性特征,但其强度随温度的升高而降低,在15℃时有强度突变点;连续升温证明,由AEO12/水体系形成的不连续立方相在21.8-22.5℃存在玻璃态转化现象。
The rheological properties of two different cubic lyotropic liquid crystal formed from nonylphenol ethoxylate- 10( NP- 10) and dodecylphenol ethoxylate( AEO12 ) in water were studied, especially the effect of temperature on the linear viscoelasticity of two different cubic phase was detected. For the V form cubic liquid crystal formed from NP - 10/H2O3, the bi-continuous liquid crystal keeps characteristic viscoelasticity between 5 - 23.5 ℃ ,but there is a decrement of strength with temperature and has a broken point in strength at 15 ℃. The I form cubic liquid crystal formed from AEO12/H2O exhibits a glassy transition between 21.8 - 22.5 ℃ during continuous temperature increase.
出处
《精细化工》
EI
CAS
CSCD
北大核心
2006年第9期863-866,共4页
Fine Chemicals
基金
泰山学院引进人才项目(Y05-2-06)~~
关键词
非离子型表面活性剂
溶致液晶
流变性
nonionic surfactant
lyotropic liquid crystal
rheological property