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温度对两种不同立方相液晶流变性的影响 被引量:4

Effect of Temperature on the Rheology of Two Different Cubic Lyotropic Liquid Crystals
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摘要 分别研究了温度对壬基酚聚氧乙烯醚(NP-10)/水体系和十二烷基聚氧乙烯醚(AEO12)/水体系形成的立方相液晶线性黏弹性的影响。5~23.5℃,NP-10/水体系形成的双连续立方相表现出明显的黏弹性特征,但其强度随温度的升高而降低,在15℃时有强度突变点;连续升温证明,由AEO12/水体系形成的不连续立方相在21.8-22.5℃存在玻璃态转化现象。 The rheological properties of two different cubic lyotropic liquid crystal formed from nonylphenol ethoxylate- 10( NP- 10) and dodecylphenol ethoxylate( AEO12 ) in water were studied, especially the effect of temperature on the linear viscoelasticity of two different cubic phase was detected. For the V form cubic liquid crystal formed from NP - 10/H2O3, the bi-continuous liquid crystal keeps characteristic viscoelasticity between 5 - 23.5 ℃ ,but there is a decrement of strength with temperature and has a broken point in strength at 15 ℃. The I form cubic liquid crystal formed from AEO12/H2O exhibits a glassy transition between 21.8 - 22.5 ℃ during continuous temperature increase.
出处 《精细化工》 EI CAS CSCD 北大核心 2006年第9期863-866,共4页 Fine Chemicals
基金 泰山学院引进人才项目(Y05-2-06)~~
关键词 非离子型表面活性剂 溶致液晶 流变性 nonionic surfactant lyotropic liquid crystal rheological property
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参考文献12

  • 1J C van der Pas.Vlaardingen liquid detergents[J].Tenside Surf Det,1991,28(3):158-162.
  • 2H Krussman,R Bercovici.Detergency at low temperatures using combinations of nonionic surfactants and medium chain alcohols[J].Tenside Surf Det,1993,30(3):99-103.
  • 3J S Beck,C Vartuli,W J Roth,et al.A new family of mesoporous molecular sieves prepared with liquid crystal templates[J].J Am Chem Soc,1992,114:10834-10843.
  • 4Warr G G,Chem C M.Steady shear behavior of ternary bicontinuous cubic phases,in "structure and flow in surfactants solutions"[J].American Chemical Society,1994,307-317.
  • 5Jones J L,Mcleish T C B.Concentration fluctuations in surfactant cubic phases:theory,rheology and light scattering[J].Langmuir,1999,15:7495-7503.
  • 6Radiman S,Toprakcioglu C,Mcleish T C B.Rheological study of ternary cubic phases[J].Langmuir,1994,10:61-67.
  • 7Jones J L,Mcleish T C B.Rheological response of surfactant cubic phases[J].Langmuir,1995,11:785-792.
  • 8冯尚华,王红霞,张高勇,谢新玲.NP-10/硝酸钠水溶液体系的相行为与流变性[J].精细化工,2003,20(12):738-741. 被引量:7
  • 9冯尚华,王红霞,张高勇,谢新玲,台秀梅,史修启.NP-10/硝酸钠水溶液体系层状液晶的流变性[J].日用化学工业,2004,34(3):147-150. 被引量:4
  • 10Gemma Montalvo,Mercedes Valinente and Elvira Rodenas.Study of the phase diagram of the CTAB/benzyl alcohol/water system.[J].J Coll Inter Sci,1995,172:494-501.

二级参考文献16

  • 1VAN DER PAS J C, VIAARDINGEN. Liquid detergents [J]. Tenside Surf Det, 1991, 28 (3): 158- 162.
  • 2MONTALVO G, VALIENTE M, RODENAS E. Rheological properties of the L phase and the hexagonal, lamellar, cubic liquid crystals of the CTAB/benzyl alcohol/water system [J]. Langmuir, 1996, 12:5 202-5208.
  • 3VERSLUIS P, VAN DE PAS J C. Microstructure and rheology of lamellar lquid crystalline phases [J]. Langmuir, 1997, 13: 5732-5738.
  • 4NéMETH ZS, HALáSZ L, PáKIBJáS J, et al. Rheological behavior of a lamellar liquid crystalline surfactant- water system[ J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1998,145:107- 119.
  • 5NéMETH ZS, PáLINKáS J, HALáSZ L, et al. Rheological and structural properties of binary nonionic surfactant - water lamellar systems [ J].Tenside Sur Det, 1999, 36 (2): 88-95.
  • 6PANIZZA, D ROUX, V VUILAUME, et al. Viscoelasticity of the onion phase [J]. Langmuir, 1996, 12: 248-252.
  • 7LAUGER J, WEIGEL R, BERGER K, et al. Rheo- small- anglelight- scattering investigation of shear- induced structural changes in a lyotropic lamellar phase [ J ]. J Colloid and Interface Science, 1996,181: 521 - 529.
  • 8EUGENE E PASHKOVSKI, JAMES G MASTERS, MEGRETEAB A.Viscoelastic scaling of colloidal gels in polymer solutions [J]. Langmuir,2003, 19: 3589-3595.
  • 9WANG H X, ZHANG G Y, MU J H, et al. Effect of temperature and surfactant concentration on rheological behavior of mesophases [J]. Tenside Surf Det, 2003, 40 (1): 1 - 7.
  • 10VERSLUIS P, VAN DE PAS J C, MELLE MAJ. Microstructrure and rheology of lamellar liquid crystalline phases [J]. Langmuir, 1997, 13:5 732 - 5 738.

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